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Optimizing the generation of narrow polydispersity ‘arm-first’ star polymers made using RAFT polymerization
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Ferreira, Julien, Syrett, Jay A., Whittaker, Michael R., Haddleton, David M., Davis, Thomas P. and Boyer, Cyrille (2011) Optimizing the generation of narrow polydispersity ‘arm-first’ star polymers made using RAFT polymerization. Polymer Chemistry, Vol.2 (No.8). pp. 1671-1677. doi:10.1039/c1py00102g ISSN 1759-9954.
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Official URL: http://dx.doi.org/10.1039/c1py00102g
Abstract
In this article, the synthesis of well-defined, narrow polydispersity (PDI < 1.2) star polymers via RAFT polymerisation is detailed. An 'arm-first' method is described using a crosslinked nanogel core. The synthetic conditions and variables were thoroughly investigated and optimised so that nearly quantitative arm incorporation was found to occur. The parameters studied included polymerization time, the arm molecular weight, and the nature of the solvent and cross-linker.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry T Technology > TP Chemical technology |
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Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Polymerization, Polyethylene oxide, Cyclodextrins, Block copolymers, Drug delivery systems, Rheology | ||||
Journal or Publication Title: | Polymer Chemistry | ||||
Publisher: | Royal Society of Chemistry | ||||
ISSN: | 1759-9954 | ||||
Official Date: | 2011 | ||||
Dates: |
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Volume: | Vol.2 | ||||
Number: | No.8 | ||||
Page Range: | pp. 1671-1677 | ||||
DOI: | 10.1039/c1py00102g | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access | ||||
Funder: | Australian Research Council (ARC) | ||||
Grant number: | DP1092640 (ARC), DP110104251 (ARC) |
Data sourced from Thomson Reuters' Web of Knowledge
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