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Acetyl halide initiator screening for the cationic ring-opening polymerization of 2-ethyl-2-oxazoline
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Paulus, Renzo M., Becer, C. Remzi, Hoogenboom, Richard and Schubert, Ulrich S. (2008) Acetyl halide initiator screening for the cationic ring-opening polymerization of 2-ethyl-2-oxazoline. Macromolecular Chemistry and Physic, Vol.209 (No.8). pp. 794-800. doi:10.1002/macp.200700506 ISSN 1022-1352.
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Official URL: http://dx.doi.org/10.1002/macp.200700506
Abstract
Kinetic investigations on the cationic ring-opening polymerization of 2-ethyl-2-oxazoline were conducted using acetyl chloride, acetyl bromide, and acetyl iodide as initiators. Various polymerization temperatures ranging from 80 to 220 °C were applied under microwave irradiation. The resulting polymerization mixtures were characterized with GC and GPC for the determination of monomer conversion and molecular weight distribution, respectively. Well defined polymers with narrow molecular weight distributions ( = 6 000 Dalton, PDI ≈ 1.10) were obtained with all three initiators.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Ring-opening polymerization, Addition polymerization, Monomers | ||||
Journal or Publication Title: | Macromolecular Chemistry and Physic | ||||
Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||
ISSN: | 1022-1352 | ||||
Official Date: | 2008 | ||||
Dates: |
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Volume: | Vol.209 | ||||
Number: | No.8 | ||||
Page Range: | pp. 794-800 | ||||
DOI: | 10.1002/macp.200700506 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Funder: | Dutch Polymer Institute (DPI), Fonds der Chemischen Industrie (Germany) | ||||
Grant number: | 502 (DPI) |
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