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The importance of the N–H bond in Ru/TsDPEN complexes for asymmetric transfer hydrogenation of ketones and imines
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Soni, Rina, Cheung, Fung Kei, Clarkson, Guy J., Martins, Jose E. D., Graham, Mark A. and Wills, Martin (2011) The importance of the N–H bond in Ru/TsDPEN complexes for asymmetric transfer hydrogenation of ketones and imines. Organic & Biomolecular Chemistry, 9 (9). pp. 3290-3294. doi:10.1039/c1ob05208j ISSN 1477-0520.
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WRAP_9574780-ch-280915-ob-art-02-2011-005208_updated_feb_2011 (1).pdf - Accepted Version - Requires a PDF viewer. Download (725Kb) | Preview |
Official URL: http://dx.doi.org/10.1039/C1OB05208J
Abstract
Ru(II) complexes of TsDPEN containing two alkyl groups on the non-tosylated nitrogen atom are poor catalysts for asymmetric transfer hydrogenation of ketones and imines; this observation provides direct evidence for the importance of the N–H interaction in the transition state for ketone reduction.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Hydrogenation, Ketones, Imines, Ruthenium | ||||
Journal or Publication Title: | Organic & Biomolecular Chemistry | ||||
Publisher: | Royal Society of Chemistry | ||||
ISSN: | 1477-0520 | ||||
Official Date: | 2011 | ||||
Dates: |
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Volume: | 9 | ||||
Number: | 9 | ||||
Page Range: | pp. 3290-3294 | ||||
DOI: | 10.1039/c1ob05208j | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access | ||||
Date of first compliant deposit: | 18 December 2015 | ||||
Date of first compliant Open Access: | 18 December 2015 | ||||
Funder: | University of Warwick , Engineering and Physical Sciences Research Council (EPSRC) , AstraZeneca (Firm) | ||||
Grant number: | EP/F019424 (EPSRC) |
Data sourced from Thomson Reuters' Web of Knowledge
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