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Amino-borane oligomers bound to a Rh(i) metal fragment
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Dallanegra, Romaeo, Chaplin, Adrian B., Tsim, Jennifer and Weller, Andrew S. (2010) Amino-borane oligomers bound to a Rh(i) metal fragment. Chemical Communications, Vol.46 (No.18). pp. 3092-3094. doi:10.1039/c003055d ISSN 1359-7345.
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Official URL: http://dx.doi.org/10.1039/c003055d
Abstract
Coordination complexes of previously observed intermediates, H(3)B center dot NMe(2)BH(2)center dot NMe(2)H and [H(2)BNMeH](3), in the transition metal catalysed dehydrocoupling of H(3)B center dot NMe(2)H and H(3)B center dot NMeH(2) have been isolated and structurally characterised using the [Rh{PR(2)'(eta(2)-C(5)H(7))}](+) fragment. Their onward reactivity shows that further dehydrogenation is not a simple intramolecular process.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Boranes, Amines, Complex compounds, Oligomers, Rhodium, Catalysis, Dehydrogenation | ||||
Journal or Publication Title: | Chemical Communications | ||||
Publisher: | Royal Society of Chemistry | ||||
ISSN: | 1359-7345 | ||||
Official Date: | 14 May 2010 | ||||
Dates: |
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Volume: | Vol.46 | ||||
Number: | No.18 | ||||
Page Range: | pp. 3092-3094 | ||||
DOI: | 10.1039/c003055d | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access |
Data sourced from Thomson Reuters' Web of Knowledge
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