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A dynamic performance model for redox-flow batteries involving soluble species
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Shah, Akeel A., Wattsmith, M. and Walsh, F. C. (2008) A dynamic performance model for redox-flow batteries involving soluble species. Electrochimica Acta, Vol.53 (No.27). pp. 8087-8100. doi:10.1016/j.electacta.2008.05.067 ISSN 0013-4686.
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Official URL: http://dx.doi.org/10.1016/j.electacta.2008.05.067
Abstract
A transient modelling framework for a vanadium redox-flow battery (RFB) is developed and experiments covering a range of vanadium concentration and electrolyte flow rate are conducted. The two-dimensional model is based on a comprehensive description of mass, charge and momentum transport and conservation, and is combined with a global kinetic model for reactions involving vanadium species. The model is validated against the experimental data and is used to study the effects of variations in concentration, electrolyte flow rate and electrode porosity. Extensions to the model and future work are suggested.
Item Type: | Journal Article | ||||
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Subjects: | T Technology > TA Engineering (General). Civil engineering (General) T Technology > TK Electrical engineering. Electronics Nuclear engineering |
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Divisions: | Faculty of Science, Engineering and Medicine > Engineering > Engineering | ||||
Library of Congress Subject Headings (LCSH): | Flow batteries, Storage batteries -- Design and construction, Vanadium -- Electric properties, Electrolytic cells, Oxidation-reduction reaction, Energy conversion | ||||
Journal or Publication Title: | Electrochimica Acta | ||||
Publisher: | Pergamon | ||||
ISSN: | 0013-4686 | ||||
Official Date: | 15 November 2008 | ||||
Dates: |
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Volume: | Vol.53 | ||||
Number: | No.27 | ||||
Number of Pages: | 14 | ||||
Page Range: | pp. 8087-8100 | ||||
DOI: | 10.1016/j.electacta.2008.05.067 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access |
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