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Physical methods for the preparation of hybrid nanocomposite polymer latex particles
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Teixeira, Roberto F. A. and Bon, Stefan Antonius Franciscus (2010) Physical methods for the preparation of hybrid nanocomposite polymer latex particles. In: Hybrid latex particles : preparation with (mini)emulsion polymerization. Advances in Polymer Science, Vol.233 . Berlin: Springer, pp. 19-52. ISBN 9783642160608
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Official URL: http://dx.doi.org/10.1007/12_2010_65
Abstract
In this chapter, we will highlight conceptual physical approaches towards the fabrication of nanocomposite polymer latexes in which each individual latex particle contains one or more "hard" nanoparticles, such as clays, silicates, titanates, or other metal(oxides). By "physical approaches" we mean that the "hard" nanoparticles are added as pre-existing entities, and are not synthesized in situ as part of the nanocomposite polymer latex fabrication process. We will narrow our discussion to focus on physical methods that rely on the assembly of nanoparticles onto the latex particles after the latex particles have been formed, or its reciprocal analogue, the adhesion of polymer onto an inorganic nanoparticle. First, will discuss the phenomenon of heterocoagulation and its various driving forces, such as electrostatic interactions, the hydrophobic effect, and secondary molecular interactions. We will then address methods that involve assembly of nanoparticles onto or around the more liquid precursors (i.e., swollen/growing latex particles or monomer droplets). We will focus on the phenomenon of Pickering stabilization. We will then discuss features of particle interaction with soft interfaces, and see how the adhesion of particles onto emulsion droplets can be applied in suspension, miniemulsion, and emulsion polymerization. Finally, we will very briefly mention some interesting methods that make use of interface-driven templating for making well-defined assembled clusters and supracolloidal structures.
Item Type: | Book Item | ||||
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Subjects: | Q Science > QD Chemistry T Technology > TA Engineering (General). Civil engineering (General) |
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Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Colloids, Coagulation, Nanocomposites (Materials), Stabilizing agents, Latex, Synthetic, Self-assembly (Chemistry), Polymers | ||||
Series Name: | Advances in Polymer Science | ||||
Journal or Publication Title: | HYBRID LATEX PARTICLES: PREPARATION WITH (MINI) EMULSION POLYMERIZATION | ||||
Publisher: | Springer | ||||
Place of Publication: | Berlin | ||||
ISBN: | 9783642160608 | ||||
ISSN: | 0065-3195 | ||||
Book Title: | Hybrid latex particles : preparation with (mini)emulsion polymerization | ||||
Official Date: | 2010 | ||||
Dates: |
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Volume: | Vol.233 | ||||
Number of Pages: | 287 | ||||
Page Range: | pp. 19-52 | ||||
DOI: | 10.1007/12-2010-65 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access |
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