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Resonant X-ray emission spectroscopy reveals d–d ligand-field states involved in the self-assembly of a square-planar platinum complex
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Garino, Claudio, Gallo, Erik, Smolentsev, Nikolay, Glatzel, Pieter, Gobetto, Roberto, Lamberti, Carlo, Sadler, P. J. and Salassa, Luca (2012) Resonant X-ray emission spectroscopy reveals d–d ligand-field states involved in the self-assembly of a square-planar platinum complex. Physical Chemistry Chemical Physics, Vol.14 (No.44). pp. 15278-15281. doi:10.1039/c2cp42451g ISSN 1463-9076.
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WRAP_Salassa_497_salassa_pccp_2012.pdf - Accepted Version Download (959Kb) | Preview |
Official URL: http://dx.doi.org/10.1039/c2cp42451g
Abstract
Resonant X-ray Emission Spectroscopy (RXES) is used to characterize the ligand field states of the prototypic self-assembled square-planar complex, [Pt(tpy)Cl]Cl (tpy=2,2′:6′,2′′-terpyridine), and determine the effect of weak metal-metal and π-π interactions on their energy. © 2012 the Owner Societies.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Self-assembly (Chemistry), X-ray spectroscopy, Platinum, Transition metal complexes, Supramolecular chemistry | ||||
Journal or Publication Title: | Physical Chemistry Chemical Physics | ||||
Publisher: | Royal Society of Chemistry | ||||
ISSN: | 1463-9076 | ||||
Official Date: | 28 November 2012 | ||||
Dates: |
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Volume: | Vol.14 | ||||
Number: | No.44 | ||||
Page Range: | pp. 15278-15281 | ||||
DOI: | 10.1039/c2cp42451g | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access | ||||
Date of first compliant deposit: | 23 December 2015 | ||||
Date of first compliant Open Access: | 23 December 2015 | ||||
Funder: | European Synchrotron Radiation Facility (ESRF), European Research Council (ERC), Spain. Ministerio de Ciencia e Innovación (MICINN) | ||||
Grant number: | CH3108 (ESRF), 247450 (ERC), RYC-2011-07787 (MICINN) |
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