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Effects of measurement materials and oxygen partial pressure on the viscosity of synthetic Eastern and Western United States coal slags
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Zhu, Jingxi, Kaneko, Tetsuya Kenneth, Mu, Haoyuan, Bennett, James P. and Sridhar, Seetharaman (2012) Effects of measurement materials and oxygen partial pressure on the viscosity of synthetic Eastern and Western United States coal slags. Energy & Fuels, Vol.26 (No.7). pp. 4465-4474. doi:10.1021/ef300632x ISSN 0887-0624.
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Official URL: http://dx.doi.org/10.1021/ef300632x
Abstract
The viscosity of the molten ash (slag) resulting from the mineral constituents in carbon feedstock used in slagging gasifiers is critical for controlling the gasification process. The viscosity of two synthetic slags with compositions resembling the mineral impurities in average eastern and western coal feedstock was examined at temperatures from 1300–1500 °C using a rotating bob viscometer. A few combinations of atmospheres and experimental materials were investigated with respect to one another to determine slag viscosity. A CO/CO2 atmosphere (CO/CO2 = 1.8, corresponding to a PO2 = 10–8 atm) is required to sustain ferrous ions in FeO-containing slags, an environment that is oxidizing to most metals. Iron oxide in the slag prevents usage of Fe parts. In unpurified Ar, the Fe metal surface oxidizes. Using purified argon prevents iron measurement components from oxidation; however, the metallic surfaces act as nucleation sites for the reduction of the Fe oxide in the slag into metallic Fe. Dissolution of ceramic materials into the slag, including Al2O3 and ZrO2, occurs in both atmospheres. Therefore, evaluating slag properties in the laboratory is challenging. The measured viscosities of two synthetic slags in this study diverged depending upon material selection. This difference is likely attributable to container/spindle-slag interactions. Viscosity measurements of the eastern coal slag using all ceramic parts agreed best with FactSage prediction above 1350 °C, with an average activation energy of 271.2 kJ. For western coal slag, the dissolution of container/spindle materials was substantial during the measurement, with precipitation of crystalline phase noted. The experimental viscosity data of the western coal slag agreed best with Kalmanovitch prediction above 1350 °C. The activation energy changed dramatically for both data sets of western coal slag, likely indicating the Newtonian-to-non-Newtonian transition.
Item Type: | Journal Article | ||||
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Divisions: | Faculty of Science, Engineering and Medicine > Engineering > WMG (Formerly the Warwick Manufacturing Group) | ||||
Journal or Publication Title: | Energy & Fuels | ||||
Publisher: | American Chemical Society | ||||
ISSN: | 0887-0624 | ||||
Official Date: | 19 July 2012 | ||||
Dates: |
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Volume: | Vol.26 | ||||
Number: | No.7 | ||||
Page Range: | pp. 4465-4474 | ||||
DOI: | 10.1021/ef300632x | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access |
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