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The importance of ligand reactions in Cu(0)-mediated living radical polymerisation of acrylates
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Anastasaki, Athina, Waldron, Christopher, Wilson, Paul, McHale, Ronan and Haddleton, David M. (2013) The importance of ligand reactions in Cu(0)-mediated living radical polymerisation of acrylates. Polymer Chemistry, Volume 4 (Number 9). pp. 2672-2675. doi:10.1039/c3py00270e ISSN 1759-9954.
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Official URL: http://dx.doi.org/10.1039/C3PY00270E
Abstract
Ligand mediated termination events occur during the homo-polymerisation of methyl (MA) and butyl (BA) acrylate under SET-LRP (Cu(0) mediated) conditions. Careful optimization of [initiator]/[ligand] (Me6Tren) ratios is required to reduce termination in order to achieve optimum polymerisation.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
| Journal or Publication Title: | Polymer Chemistry | ||||
| Publisher: | Royal Society of Chemistry | ||||
| ISSN: | 1759-9954 | ||||
| Official Date: | March 2013 | ||||
| Dates: |
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| Volume: | Volume 4 | ||||
| Number: | Number 9 | ||||
| Page Range: | pp. 2672-2675 | ||||
| DOI: | 10.1039/c3py00270e | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access |
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