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An investigation into thiol–ene surface chemistry of poly(ethylene glycol) acrylates, methacrylates and CCTP polymers via quartz crystal microbalance with dissipation monitoring (QCM-D)
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Slavin, Stacy and Haddleton, David M. (2012) An investigation into thiol–ene surface chemistry of poly(ethylene glycol) acrylates, methacrylates and CCTP polymers via quartz crystal microbalance with dissipation monitoring (QCM-D). Soft Matter, Volume 8 (Number 40). p. 10388. doi:10.1039/c2sm26304a ISSN 1744-683X.
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Official URL: http://dx.doi.org/10.1039/C2SM26304A
Abstract
Thiol-ene reactions at surfaces have been investigated, comparing poly(ethylene glycol) (PEG) acrylate and methacrylate monomers with polymers made by cobalt catalysed chain transfer polymerisation (CCTP) using QCM-D. Thiolated surfaces were generated on silicon dioxide QCM-D sensors, with PEG monomers and polymers subsequently passed over the thiolated surface to study the thiol-ene reaction in the absence and presence of tris(2-carboxyethyl) phosphine, TCEP as catalyst.
Item Type: | Journal Article | ||||
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Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Journal or Publication Title: | Soft Matter | ||||
Publisher: | Royal Society of Chemistry | ||||
ISSN: | 1744-683X | ||||
Official Date: | 28 October 2012 | ||||
Dates: |
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Volume: | Volume 8 | ||||
Number: | Number 40 | ||||
Page Range: | p. 10388 | ||||
DOI: | 10.1039/c2sm26304a | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published |
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