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The influence of phosphine cone angle on the synthesis and structures of [Rh(PR3)(Binor–S)]+ complexes that show C–C sigma interactions
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Chaplin, Adrian B. and Weller, Andrew S. (2013) The influence of phosphine cone angle on the synthesis and structures of [Rh(PR3)(Binor–S)]+ complexes that show C–C sigma interactions. Journal of Organometallic Chemistry, Volume 730 . pp. 90-94. doi:10.1016/j.jorganchem.2012.09.013 ISSN 0022-328X.
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Official URL: http://dx.doi.org/10.1016/j.jorganchem.2012.09.013
Abstract
Complexes that show C–C···Rh sigma interactions have been synthesized and characterised by NMR spectroscopy and X–ray diffraction: [Rh(PR3)(Binor–S)][BArF4], R = PtBu2Me, PCy2Ph; Ar = C6H3(CF3)2, Binor–S = 1,2,4,5,6,8-dimetheno-S-indacene. These studies, in concert with previously published work, show that there is a rather narrow window of phosphine steric profile that supports the isolation of these interesting complexes, with the phosphine cone angle lying between 160° and 170°.
Item Type: | Journal Article | ||||
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Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Journal or Publication Title: | Journal of Organometallic Chemistry | ||||
Publisher: | Elsevier S.A. | ||||
ISSN: | 0022-328X | ||||
Official Date: | 2013 | ||||
Dates: |
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Volume: | Volume 730 | ||||
Page Range: | pp. 90-94 | ||||
DOI: | 10.1016/j.jorganchem.2012.09.013 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access |
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