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Use of triazole-ring formation to attach a Ru/TsDPEN complex for asymmetric transfer hydrogenation to a soluble polymer
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Zammit, Charlotte M. and Wills, Martin (2013) Use of triazole-ring formation to attach a Ru/TsDPEN complex for asymmetric transfer hydrogenation to a soluble polymer. Tetrahedron : Asymmetry, 24 (13-14). pp. 844-852. doi:10.1016/j.tetasy.2013.05.022 ISSN 0957-4166.
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Official URL: http://dx.doi.org/10.1016/j.tetasy.2013.05.022
Abstract
The cycloaddition of a chiral ligand containing a terminal alkyne to a soluble polymer containing an azide provides a convenient means for the attachment of an asymmetric transfer hydrogenation catalyst to a soluble polymer support. Using these ligands in complexes with Ru(II), gave good results in terms of conversion and enantioselectivity (up to 95% ee) in ketone reduction reactions.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Hydrogenation, Triazoles, Ruthenium catalysts | ||||
Journal or Publication Title: | Tetrahedron : Asymmetry | ||||
Publisher: | Pergamon | ||||
ISSN: | 0957-4166 | ||||
Official Date: | 31 July 2013 | ||||
Dates: |
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Volume: | 24 | ||||
Number: | 13-14 | ||||
Number of Pages: | 9 | ||||
Page Range: | pp. 844-852 | ||||
DOI: | 10.1016/j.tetasy.2013.05.022 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access | ||||
Date of first compliant deposit: | 26 December 2015 | ||||
Date of first compliant Open Access: | 26 December 2015 | ||||
Funder: | European Union (EU) |
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