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Copper-mediated controlled radical polymerization under biological conditions : SET-LRP in blood serum
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Zhang, Qiang, Li, Zaidong, Wilson, Paul and Haddleton, David M. (2013) Copper-mediated controlled radical polymerization under biological conditions : SET-LRP in blood serum. Chemical Communications, Volume 49 (Number 59). pp. 6608-6610. doi:10.1039/c3cc43731k ISSN 1359-7345.
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Official URL: http://dx.doi.org/10.1039/C3CC43731K
Abstract
The polymerization of hydrophilic monomers is reported utilizing Cu(0)-mediated living radical polymerization, SET-LRP. Highly active Cu(0) is formed in situ as a result of rapid disproportionation of [Cu(I)(Me6-Tren)Br] in serum. Disproportionation and homogenous controlled radical polymerization (PDI 1.09–1.25) are performed for the first time in blood (sheep) serum.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
| Journal or Publication Title: | Chemical Communications | ||||
| Publisher: | Royal Society of Chemistry | ||||
| ISSN: | 1359-7345 | ||||
| Official Date: | 11 July 2013 | ||||
| Dates: |
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| Volume: | Volume 49 | ||||
| Number: | Number 59 | ||||
| Page Range: | pp. 6608-6610 | ||||
| DOI: | 10.1039/c3cc43731k | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Restricted or Subscription Access |
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