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Copper-mediated controlled radical polymerization under biological conditions : SET-LRP in blood serum

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Zhang, Qiang, Li, Zaidong, Wilson, Paul and Haddleton, David M. (2013) Copper-mediated controlled radical polymerization under biological conditions : SET-LRP in blood serum. Chemical Communications, Volume 49 (Number 59). pp. 6608-6610. doi:10.1039/c3cc43731k ISSN 1359-7345.

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Official URL: http://dx.doi.org/10.1039/C3CC43731K

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Abstract

The polymerization of hydrophilic monomers is reported utilizing Cu(0)-mediated living radical polymerization, SET-LRP. Highly active Cu(0) is formed in situ as a result of rapid disproportionation of [Cu(I)(Me6-Tren)Br] in serum. Disproportionation and homogenous controlled radical polymerization (PDI 1.09–1.25) are performed for the first time in blood (sheep) serum.

Item Type: Journal Article
Divisions: Faculty of Science, Engineering and Medicine > Science > Chemistry
Journal or Publication Title: Chemical Communications
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Official Date: 11 July 2013
Dates:
DateEvent
11 July 2013Published
Volume: Volume 49
Number: Number 59
Page Range: pp. 6608-6610
DOI: 10.1039/c3cc43731k
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access

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