The Library
Poly(acrylates) via SET-LRP in a continuous tubular reactor
Tools
Tools
Tools
Burns, James A., Houben, Claudia, Anastasaki, Athina, Waldron, Christopher, Lapkin, Alexei and Haddleton, David M. (2013) Poly(acrylates) via SET-LRP in a continuous tubular reactor. Polymer Chemistry, Volume 4 (Number 17). pp. 4809-4813. doi:10.1039/c3py00833a ISSN 1759-9954.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Official URL: http://dx.doi.org/10.1039/c3py00833a
Abstract
A simple, easy to construct, bench-top plug flow reactor consisting of PTFE tubing with a Cu(0) threaded core (wire) was used to perform SET-LRP of methyl acrylate. The reaction was optimized by changing the residence time within the flow reactor. Both changing the flow reactor length and changing the flow rate was seen to control the resultant polymer molecular weight. Using a 20 cm reactor length, 95% conversion of monomer was seen at a flow rate of 0.1 mL min-1. The polymers formed had narrow molecular weight distributions (PDI< 1.2), and very high ω-chain end fidelity, as seen by both 1H NMR and MALDI-TOF MS.
| Item Type: | Journal Article | ||||
|---|---|---|---|---|---|
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
| Journal or Publication Title: | Polymer Chemistry | ||||
| Publisher: | Royal Society of Chemistry | ||||
| ISSN: | 1759-9954 | ||||
| Official Date: | 2013 | ||||
| Dates: |
|
||||
| Volume: | Volume 4 | ||||
| Number: | Number 17 | ||||
| Page Range: | pp. 4809-4813 | ||||
| DOI: | 10.1039/c3py00833a | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Access rights to Published version: | Open Access (Creative Commons) |
Request changes or add full text files to a record
Repository staff actions (login required)
 |
View Item |
