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Synthesis and aggregation of double hydrophilic diblock glycopolymers via aqueous SET-LRP
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Zhang, Qiang, Wilson, Paul, Anastasaki, Athina, McHale, Ronan and Haddleton, David M. (2014) Synthesis and aggregation of double hydrophilic diblock glycopolymers via aqueous SET-LRP. ACS Macro Letters, Volume 3 (Number 5). pp. 491-495. doi:10.1021/mz5001724
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Official URL: http://dx.doi.org/10.1021/mz5001724
Abstract
A chemically unprotected mannose-containing acrylate (ManA) monomer was synthesized and polymerized by Cu(0)-mediated radical polymerization in water (SET-LRP). One-pot block copolymerization was achieved upon addition of a solution of N-isopropylacrylamide (NIPAm) or diethylene glycol ethyl ether acrylate (DEGEEA) forming thermoresponsive double hydrophilic diblock glycopolymers which revealed self-assembly properties in aqueous solution forming well-defined, sugar-decorated nanoparticles.
| Item Type: | Journal Item | ||||||
|---|---|---|---|---|---|---|---|
| Divisions: | Faculty of Science > Chemistry | ||||||
| Journal or Publication Title: | ACS Macro Letters | ||||||
| Publisher: | American Chemical Society | ||||||
| ISSN: | 2161-1653 | ||||||
| Official Date: | 20 May 2014 | ||||||
| Dates: |
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| Volume: | Volume 3 | ||||||
| Number: | Number 5 | ||||||
| Page Range: | pp. 491-495 | ||||||
| DOI: | 10.1021/mz5001724 | ||||||
| Status: | Peer Reviewed | ||||||
| Publication Status: | Published | ||||||
| Access rights to Published version: | Restricted or Subscription Access |
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