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Synthesis and aggregation of double hydrophilic diblock glycopolymers via aqueous SET-LRP

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Zhang, Qiang, Wilson, Paul, Anastasaki, Athina, McHale, Ronan and Haddleton, David M. (2014) Synthesis and aggregation of double hydrophilic diblock glycopolymers via aqueous SET-LRP. ACS Macro Letters, Volume 3 (Number 5). pp. 491-495. doi:10.1021/mz5001724

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Official URL: http://dx.doi.org/10.1021/mz5001724

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Abstract

A chemically unprotected mannose-containing acrylate (ManA) monomer was synthesized and polymerized by Cu(0)-mediated radical polymerization in water (SET-LRP). One-pot block copolymerization was achieved upon addition of a solution of N-isopropylacrylamide (NIPAm) or diethylene glycol ethyl ether acrylate (DEGEEA) forming thermoresponsive double hydrophilic diblock glycopolymers which revealed self-assembly properties in aqueous solution forming well-defined, sugar-decorated nanoparticles.

Item Type: Journal Item
Divisions: Faculty of Science, Engineering and Medicine > Science > Chemistry
Journal or Publication Title: ACS Macro Letters
Publisher: American Chemical Society
ISSN: 2161-1653
Official Date: 20 May 2014
Dates:
DateEvent
20 May 2014Published
9 May 2014Available
Volume: Volume 3
Number: Number 5
Page Range: pp. 491-495
DOI: 10.1021/mz5001724
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access

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