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Kinetic and structural studies on 'tethered' Ru(II) arene ketone reduction catalysts
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Cheung, Fung Kei, Clarke, Adam J., Clarkson, Guy J., Fox, David J., Graham, Mark A., Lin, Changxue, Crivillé, Adriana Lorente and Wills, Martin (2010) Kinetic and structural studies on 'tethered' Ru(II) arene ketone reduction catalysts. Dalton Transactions, Vol.39 (No.5). pp. 1395-1402. doi:10.1039/b915932k ISSN 1477-9226.
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Official URL: http://dx.doi.org/10.1039/b915932k
Abstract
A series of kinetic and structural investigations on ruthenium-based catalysts for asymmetric transfer hydrogenation (ATH) of ketones are reported. A method is reported for monitoring the formation of ruthenium hydride species in real time using H-1 NMR spectroscopy.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Library of Congress Subject Headings (LCSH): | Catalysts -- Analysis, Ruthenium, Ketones | ||||
Journal or Publication Title: | Dalton Transactions | ||||
Publisher: | Royal Society of Chemistry | ||||
ISSN: | 1477-9226 | ||||
Official Date: | 2010 | ||||
Dates: |
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Volume: | Vol.39 | ||||
Number: | No.5 | ||||
Number of Pages: | 8 | ||||
Page Range: | pp. 1395-1402 | ||||
DOI: | 10.1039/b915932k | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access | ||||
Date of first compliant deposit: | 3 December 2015 | ||||
Date of first compliant Open Access: | 3 December 2015 | ||||
Funder: | Engineering and Physical Sciences Research Council (EPSRC), AstraZeneca (Firm), British Council | ||||
Grant number: | GR/S72214/1 (EPSRC), EP/D072182/1 (EPSRC) |
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