Garcia, Margarita, Kempe, Kristian, Haddleton, David M., Khan, Afzal and Marsh, Andrew (2015) Templated polymerizations on solid supports mediated by complementary nucleoside interactions. Polymer Chemistry, 6 . pp. 1944-1951. doi:10.1039/c4py01783h ISSN 1759-9954.

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Abstract

Template-directed radical polymerizations on solid supports are presented, which take advantage of complementary nucleoside interactions in non-polar solvents. The templates are prepared through copper-mediated living radical polymerization allowing control over the length and dispersity of the polymer bound to the support. We report a degree of control over subsequent polymerization of a complementary base pair monomer in the presence of the template not observed in its absence. Templates achieved from uridine, adenosine, cytidine and guanosine substituted methacrylate monomers were successfully prepared. Uridine derived templates were found to provide good fidelity of replication by incorporating mainly adenosine monomer in the final polymer, from a mixture of monomers. The latter was separated from its template and characterized demonstrating the preparation of polymers of approximately half of the template length. A model for the templating process is proposed.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science, Engineering and Medicine > Science > Chemistry
Library of Congress Subject Headings (LCSH):	Polymerization
Journal or Publication Title:	Polymer Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	1759-9954
Official Date:	20 March 2015
Dates:	Date Event 20 March 2015 Published 12 January 2015 Available 26 December 2014 Accepted 22 December 2014 Submitted
Volume:	6
Number of Pages:	8
Page Range:	pp. 1944-1951
DOI:	10.1039/c4py01783h
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Open Access (Creative Commons)
Date of first compliant deposit:	28 December 2015
Date of first compliant Open Access:	28 December 2015
Funder:	Engineering and Physical Sciences Research Council (EPSRC), University of Warwick Postgraduate Research Scholarship
Grant number:	GR/L71933 (EPSRC)
Related URLs:	Related dataset

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