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Towards a selective heterogeneous catalyst for glucose dehydration to 5-hydroxymethylfurfural in water : CrCl2 catalysis in a thin immobilized ionic liquid layer
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Degirmenci, Volkan, Pidko, Evgeny A., Magusin, Pieter C. M. M. and Hensen, Emiel J. M. (2011) Towards a selective heterogeneous catalyst for glucose dehydration to 5-hydroxymethylfurfural in water : CrCl2 catalysis in a thin immobilized ionic liquid layer. ChemCatChem, Volume 3 (Number 6). pp. 969-972. doi:10.1002/cctc.201000426 ISSN 1867-3880.
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Official URL: http://dx.doi.org/10.1002/cctc.201000426
Abstract
Sugar it up: Stabilization of the CrCl2 active phase in a thin layer of an ionic liquid covalently grafted to mesoporous silica results in a highly selective catalyst for the dehydration of glucose to 5-hydroxymethylfurfural (HMF) in an aqueous medium. Glucose dehydration in water by using the CrCl2-Im-SBA-15 catalyst leads to a 50 % HMF selectivity that can be further increased to up to 70 % by modifying the solvent system.
Item Type: | Journal Article | ||||
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Divisions: | Faculty of Science, Engineering and Medicine > Engineering > Engineering | ||||
Journal or Publication Title: | ChemCatChem | ||||
Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||
ISSN: | 1867-3880 | ||||
Official Date: | 14 June 2011 | ||||
Dates: |
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Volume: | Volume 3 | ||||
Number: | Number 6 | ||||
Page Range: | pp. 969-972 | ||||
DOI: | 10.1002/cctc.201000426 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access |
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