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Intramolecular transcyclometallation : the exchange of an aryl–Pt bond for an alkyl–Pt bond via an agostic intermediate
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Shaw, Paul Anthony, Phillips, Jessica M., Newman, Christopher P., Clarkson, Guy J. and Rourke, Jonathan (2015) Intramolecular transcyclometallation : the exchange of an aryl–Pt bond for an alkyl–Pt bond via an agostic intermediate. Chemical Communications, Volume 51 (Number 39). pp. 8365-8368. doi:10.1039/c5cc02355f ISSN 1359-7345.
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Official URL: http://dx.doi.org/10.1039/C5CC02355F
Abstract
Oxidation of a square-planar platinum complex leads to a five coordinate cationic intermediate that can be stabilized and trapped out via an agostic interaction with the alkyl chain of a ligand. Subsequent reaction of this species leads to the formation of an alkyl–Pt bond at the expense of an aryl–Pt bond: an intramolecular transcyclometallation.
Item Type: | Journal Article | ||||||||||
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Subjects: | Q Science > QD Chemistry | ||||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||||
Library of Congress Subject Headings (LCSH): | Chemical bonds, Intermediates (Chemistry), Carbon, Hydrogen | ||||||||||
Journal or Publication Title: | Chemical Communications | ||||||||||
Publisher: | Royal Society of Chemistry | ||||||||||
ISSN: | 1359-7345 | ||||||||||
Official Date: | 14 May 2015 | ||||||||||
Dates: |
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Volume: | Volume 51 | ||||||||||
Number: | Number 39 | ||||||||||
Page Range: | pp. 8365-8368 | ||||||||||
DOI: | 10.1039/c5cc02355f | ||||||||||
Status: | Peer Reviewed | ||||||||||
Publication Status: | Published | ||||||||||
Access rights to Published version: | Open Access (Creative Commons) | ||||||||||
Date of first compliant deposit: | 29 December 2015 | ||||||||||
Date of first compliant Open Access: | 27 April 2016 | ||||||||||
Funder: | Engineering and Physical Sciences Research Council (EPSRC), Advantage West Midlands (AWM), European Regional Development Fund (ERDF) | ||||||||||
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