The Library
Electrochemistry of tin deposition from mixed sulphate and methanesulphonate electrolyte
Tools
Low, C. T. J., Kerr, C., Barker, B. Des, Smith, J. R., Campbell, S. A. and Walsh, F. C. (2008) Electrochemistry of tin deposition from mixed sulphate and methanesulphonate electrolyte. Transactions of the IMF, 86 (3). pp. 148-152. doi:10.1179/174591908X304216 ISSN 0020-2967.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Official URL: http://dx.doi.org/10.1179/174591908X304216
Abstract
The electrodeposition of tin, at a copper surface, from a tin sulphate (0˙014 mol dm–3) electrolyte containing methanesulphonic acid (12 ˙5 vol.-%) at 295 K has been studied. Cyclic voltammetry, using potential sweep rates of 8–128 mV s–1, at a stationary copper electrode provided information on the potential ranges for tin deposition and stripping. Linear sweep voltammetry, at a copper rotating disc electrode was used to evaluate the mass transport characteristics of the system under controlled, laminar flow conditions. The changes in the limiting current density with a Sn2+ concentration of 0˙006–0˙078 mol dm–3 and an electrode rotation rate of 200–4800 rev min–1 were quantified. Randles-Sevčik and Levich equations were used to give an averaged diffusion coefficient for Sn2+ of 5˙4 × 10–6 cm2 s–1.
Item Type: | Journal Article | ||||
---|---|---|---|---|---|
Divisions: | Faculty of Science, Engineering and Medicine > Engineering > WMG (Formerly the Warwick Manufacturing Group) | ||||
Journal or Publication Title: | Transactions of the IMF | ||||
Publisher: | Maney Publishing | ||||
ISSN: | 0020-2967 | ||||
Official Date: | 1 May 2008 | ||||
Dates: |
|
||||
Volume: | 86 | ||||
Number: | 3 | ||||
Page Range: | pp. 148-152 | ||||
DOI: | 10.1179/174591908X304216 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access |
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |