Lloyd, Danielle J., Nikolaou, Vasiliki, Collins, Jennifer, Waldron, Christopher, Anastasaki, Athina, Bassett, Simon, Howdle, Steven M., Blanazs, Adam, Wilson, Paul, Kempe, Kristian and Haddleton, David M. (2016) Controlled aqueous polymerization of acrylamides and acrylates and “in situ” depolymerization in the presence of dissolved CO2. Chemical Communications, 52 . pp. 6533-6536. doi:10.1039/c6cc03027k ISSN 1359-7345.

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Abstract

Aqueous copper-mediated radical polymerization of acrylamides and acrylates in carbonated water resulted in high monomer conversions (t < 10 min) before undergoing depolymerization (60 min > t > 10 min). The regenerated monomer was characterized and repolymerized following deoxygenation of the resulting solutions to reyield polymers in high conversions that exhibit low dispersities.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Science, Engineering and Medicine > Science > Chemistry
Library of Congress Subject Headings (LCSH):	Acrylamide, Acrylates, Polymerization, Copper catalysts
Journal or Publication Title:	Chemical Communications
Publisher:	Royal Society of Chemistry
ISSN:	1359-7345
Official Date:	25 April 2016
Dates:	Date Event 25 April 2016 Available 19 April 2016 Accepted 11 April 2016 Submitted
Volume:	52
Number of Pages:	5
Page Range:	pp. 6533-6536
DOI:	10.1039/c6cc03027k
Status:	Peer Reviewed
Publication Status:	Published
Access rights to Published version:	Restricted or Subscription Access
Date of first compliant deposit:	29 April 2016
Date of first compliant Open Access:	25 April 2017
Funder:	Badische Anilin- & Soda-Fabrik (BASF), Engineering and Physical Sciences Research Council (EPSRC), Lubrizol Ltd.
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