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Data for Increasing minority carrier lifetime in as-grown multicrystalline silicon by low temperature internal gettering

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Al-Amin, Mohammad and Murphy, John D. (2016) Data for Increasing minority carrier lifetime in as-grown multicrystalline silicon by low temperature internal gettering. [Dataset]

[img] Microsoft Excel (Dataset file)
WRAP_Murphy_2016-06-09 Dataset.xlsx - Published Version

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Official URL: http://wrap.warwick.ac.uk/79577

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Abstract

We report a systematic study into the effects of long low temperature (≤500 °C) annealing on the lifetime and interstitial iron distributions in as-grown multicrystalline silicon (mc-Si) from different ingot height positions. Samples are characterised in terms of dislocation density, and lifetime and interstitial iron concentration measurements are made at every stage using a temporary room temperature iodine-ethanol surface passivation scheme. Our measurement procedure allows these properties to be monitored during processing in a pseudo in situ way. Sufficient annealing at 300 °C and 400 °C increases lifetime in all cases studied, and annealing at 500 °C was only found to improve relatively poor wafers from the top and bottom of the block. We demonstrate that lifetime in poor as-grown wafers can be improved substantially by a low cost process in the absence of any bulk passivation which might result from a dielectric surface film. Substantial improvements are found in bottom wafers, for which annealing at 400 °C for 35 h increases lifetime from 5.5 μs to 38.7 μs. The lifetime of top wafers is improved from 12.1 μs to 23.8 μs under the same conditions. A correlation between interstitial iron concentration reduction and lifetime improvement is found in these cases. Surprisingly, although the interstitial iron concentration exceeds the expected solubility values, low temperature annealing seems to result in an initial increase in interstitial iron concentration, and any subsequent decay is a complex process driven not only by diffusion of interstitial iron.

Item Type: Dataset
Subjects: Q Science > QC Physics
T Technology > TK Electrical engineering. Electronics Nuclear engineering
Divisions: Faculty of Science, Engineering and Medicine > Engineering > Engineering
Library of Congress Subject Headings (LCSH): Semiconductor wafers -- Testing, Getters, Annealing of crystals
Publisher: University of Warwick, School of Engineering
Official Date: 9 June 2016
Dates:
DateEvent
9 June 2016Completion
Status: Not Peer Reviewed
Publication Status: Published
Media of Output (format): .xlsx
Access rights to Published version: Open Access (Creative Commons)
Description:

Figure 3 (a): effective lifetimes, Figure 3 (b): interstitial iron concentrations, Figure 5: dislocation density frequency distributions, Figure 6: effective lifetimes, Figure 7: interstitial iron concentrations, Figure 10: lifetime correlation with interstitial iron

Date of first compliant deposit: 9 June 2016
Date of first compliant Open Access: 9 June 2016
RIOXX Funder/Project Grant:
Project/Grant IDRIOXX Funder NameFunder ID
EP/J01768X/2[EPSRC] Engineering and Physical Sciences Research Councilhttp://dx.doi.org/10.13039/501100000266
EP/M024911/1 [EPSRC] Engineering and Physical Sciences Research Councilhttp://dx.doi.org/10.13039/501100000266
RG100076Royal Societyhttp://dx.doi.org/10.13039/501100000288
UNSPECIFIEDRoyal Academy of Engineeringhttp://dx.doi.org/10.13039/501100000287
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