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A soluble-polymer system for the asymmetric transfer hydrogenation of ketones
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UNSPECIFIED (2004) A soluble-polymer system for the asymmetric transfer hydrogenation of ketones. JOURNAL OF ORGANIC CHEMISTRY, 69 (16). pp. 5405-5412. doi:10.1021/jo049479u ISSN 0022-3263.
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Official URL: http://dx.doi.org/10.1021/jo049479u
Abstract
The appropriate combination of methaerylate polymers permits the synthesis of a soluble polymer for use in ruthenium(II)-catalyzed asymmetric transfer hydrogenation reactions. Using a 7:3 copolymer of a poly(ethylene glycol) ester and a hydroxyethyl ester, a derived ruthenium(II)/ norephedrine complex catalyses reduction of acetophenone in up to 95% yield and 81% ee.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF ORGANIC CHEMISTRY | ||||
Publisher: | AMER CHEMICAL SOC | ||||
ISSN: | 0022-3263 | ||||
Official Date: | 6 August 2004 | ||||
Dates: |
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Volume: | 69 | ||||
Number: | 16 | ||||
Number of Pages: | 8 | ||||
Page Range: | pp. 5405-5412 | ||||
DOI: | 10.1021/jo049479u | ||||
Publication Status: | Published |
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