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Chemical binding of unsaturated Fluorenes to Poly(2-chloroxylylene) thin films
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Bolognesi, Alberto, Botta, Chiara, Andicsova, Anita, Giovanella, Umberto, Arnautov, Sergey, Charmet, Jérôme, Laux, Edith and Keppner, Herbert (2009) Chemical binding of unsaturated Fluorenes to Poly(2-chloroxylylene) thin films. Macromolecular Chemistry and Physics, 210 (23). pp. 2052-2057. doi:10.1002/macp.200900321 ISSN 1022-1352.
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Official URL: http://dx.doi.org/10.1002/macp.200900321
Abstract
A series of substituted fluorenes with vinyl groups as reactive sites were synthesized and characterized. Fluorene-based polymers with vinyl groups as end chains and side chains functionalities were also prepared. In both cases, successful preparation of functionalized Parylene C films (modylayers) was achieved. The set of spectral methods used has allowed us to conclude that such functionalization is based on the chemical reaction of double bonds with xylylene radicals during deposition process. Parylene C films chemically modified with specially synthesized polyfluorenes showed PL quantum efficiency comparable with neat polyfluorenes.
Item Type: | Journal Article | ||||||||
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Divisions: | Faculty of Science, Engineering and Medicine > Engineering > WMG (Formerly the Warwick Manufacturing Group) | ||||||||
Journal or Publication Title: | Macromolecular Chemistry and Physics | ||||||||
Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||||||
ISSN: | 1022-1352 | ||||||||
Official Date: | 4 December 2009 | ||||||||
Dates: |
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Volume: | 210 | ||||||||
Number: | 23 | ||||||||
Page Range: | pp. 2052-2057 | ||||||||
DOI: | 10.1002/macp.200900321 | ||||||||
Status: | Peer Reviewed | ||||||||
Publication Status: | Published | ||||||||
Access rights to Published version: | Restricted or Subscription Access |
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