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Complexation and proton transfer by hydroxamic acids in model inhibited metallohydrolases: formation of metal hydroxamate trimers
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UNSPECIFIED (2004) Complexation and proton transfer by hydroxamic acids in model inhibited metallohydrolases: formation of metal hydroxamate trimers. INORGANIC CHEMISTRY COMMUNICATIONS, 7 (4). pp. 495-498. doi:10.1016/j.inoche.2003.12.038 ISSN 1387-7003.
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Official URL: http://dx.doi.org/10.1016/j.inoche.2003.12.038
Abstract
Reaction between the dimeric metal complexes, [M-2(mu-OAcF)(2) (OAcF)(2) (mu-H2O)(tmen)(2)], M = Co(II), Ni(II), and aceto- and benzohydroxamic acids (AHA, BHA) gives the novel trimeric complexes, [M-3(mu-OAcF)(4)(mu-RA)(2)(tmen)(2)], M=Co(II), Ni(II); RA = AA, BA, in which each hydroxamate bridges two metal centres via its deprotonated hydroxyl and the carbonyl oxygen bonds one metal centre only together with the doubly protonated salt [(tmen).2H][OAcF](2). In contrast, self-assembly from M(OAcF)(2).4H(2)O, tmen and RHA gives the dibridged hydroxamate dimers [M-2(mu-OAcF)(mu-RA)(2)(tmen)(2)] [OAcF]. (C) 2004 Elsevier B.V. All rights reserved.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | INORGANIC CHEMISTRY COMMUNICATIONS | ||||
Publisher: | ELSEVIER SCIENCE BV | ||||
ISSN: | 1387-7003 | ||||
Official Date: | April 2004 | ||||
Dates: |
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Volume: | 7 | ||||
Number: | 4 | ||||
Number of Pages: | 4 | ||||
Page Range: | pp. 495-498 | ||||
DOI: | 10.1016/j.inoche.2003.12.038 | ||||
Publication Status: | Published |
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