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Blocked isocyanates : from analytical and experimental considerations to non-polyurethane applications
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Rolph, Marianne S., Markowska, Anna L. J., Warriner, Colin N. and O'Reilly, Rachel K. (2016) Blocked isocyanates : from analytical and experimental considerations to non-polyurethane applications. Polymer Chemistry, 7 (48). pp. 7351-7364. ISSN 1759-9954.
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WRAP_C6PY01776B.pdf - Published Version - Requires a PDF viewer. Available under License Creative Commons Attribution. Download (2250Kb) | Preview |
Official URL: https://doi.org/10.1039%2Fc6py01776b
Abstract
In this review we aim to provide an introductory guide to blocked isocyanates, through discussion on different examples of blocking groups, along with experimental considerations for their application. The review brings together updated examples of functionalities used and places specific emphasis on the analytical techniques used for the determination of deblocking temperature, updating previous reviews with the newly applied technique of X-ray photoelectron spectroscopy (XPS). Additionally, we put forward a brief update on the use of blocked isocyanates for other non-traditional polyurethane based polymer applications. We also highlight the importance of matching the analytical technique to the application of the blocked isocyanate, with differences in material state and experimental parameters having a great impact on the deblocking temperature reported.
| Item Type: | Journal Article | ||||||
|---|---|---|---|---|---|---|---|
| Subjects: | T Technology > TP Chemical technology | ||||||
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||
| Library of Congress Subject Headings (LCSH): | Isocyanates , Polyurethanes , X-ray photoelectron spectroscopy | ||||||
| Journal or Publication Title: | Polymer Chemistry | ||||||
| Publisher: | Royal Society of Chemistry | ||||||
| ISSN: | 1759-9954 | ||||||
| Official Date: | 8 November 2016 | ||||||
| Dates: |
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| Volume: | 7 | ||||||
| Number: | 48 | ||||||
| Page Range: | pp. 7351-7364 | ||||||
| Status: | Peer Reviewed | ||||||
| Publication Status: | Published | ||||||
| Access rights to Published version: | Open Access (Creative Commons) | ||||||
| Date of first compliant deposit: | 31 March 2017 | ||||||
| Date of first compliant Open Access: | 4 April 2017 | ||||||
| Funder: | Atomic Weapons Research Establishment (Great Britain), Engineering and Physical Sciences Research Council (EPSRC) |
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