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Synthesis of aliphatic polycarbonates with a tuneable thermal response
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Thomas, Anthony W., Kuroishi, Paula K., Pérez-Madrigal, Maria M., Whittaker, Andrew K. and Dove, Andrew P. (2017) Synthesis of aliphatic polycarbonates with a tuneable thermal response. Polymer Chemistry, 8 (34). 5082-5090 . doi:10.1039/C7PY00358G ISSN 1759-9954.
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WRAP-synthesis-aliphatic-polycarbonates-tuneable-thermal-response-Perez Madrigal-2017.pdf - Accepted Version - Requires a PDF viewer. Download (796Kb) | Preview |
Official URL: http://dx.doi.org/10.1039/C7PY00358G
Abstract
Thermally-responsive polymers have been widely studied, however access to materials in which both the thermal response can be tuned and in which the backbone is ultimately biodegradable is limited. To this end, a range of well-defined homopolymers of 2-allyloxymethyl-2-ethyltrimethylene carbonate (AOMEC) was prepared using a dual organocatalytic ring-opening polymerisation methodology. Post-polymerisation functionalisation of PAOMEC with thiols bearing a range of functional groups was optimised via photoinitated radical thiol–ene coupling reactions. The inclusion of thiol-terminated poly(ethylene glycol) (PEG) enabled the synthesis of polycarbonates that exhibit a lower critical solution temperature (LCST). This approach enables the facile modification of the cloud point of these materials to create a library of thermally-responsive polymers, achieved by simply varying the molecular weight of the PEG chains and grafting blends of PEG to PAOMEC.
| Item Type: | Journal Article | ||||||||
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| Subjects: | Q Science > QD Chemistry T Technology > TP Chemical technology |
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| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||
| Library of Congress Subject Headings (LCSH): | Thermoresponsive polymers , Polymerization , Aliphatic compounds | ||||||||
| Journal or Publication Title: | Polymer Chemistry | ||||||||
| Publisher: | Royal Society of Chemistry | ||||||||
| ISSN: | 1759-9954 | ||||||||
| Official Date: | 14 September 2017 | ||||||||
| Dates: |
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| Volume: | 8 | ||||||||
| Number: | 34 | ||||||||
| Page Range: | 5082-5090 | ||||||||
| DOI: | 10.1039/C7PY00358G | ||||||||
| Status: | Peer Reviewed | ||||||||
| Publication Status: | Published | ||||||||
| Access rights to Published version: | Restricted or Subscription Access | ||||||||
| Date of first compliant deposit: | 15 May 2017 | ||||||||
| Date of first compliant Open Access: | 27 March 2018 | ||||||||
| Funder: | University of Warwick, Australian Institute for Bioengineering and Nanotechnology (AIBN), Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq), Horizon 2020 (European Commission) (H2020) | ||||||||
| Grant number: | 203127/2014-5 (CNPq), 703415 (H2020) |
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