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The synthesis and STM/AFM imaging of ‘Olympicene’ benzo[cd]pyrenes
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Mistry, Anish, Moreton, Ben, Schuler, Bruno, Mohn, Fabian, Meyer, Gerhard, Gross, Leo, Williams, Antony, Scott, Peter, Costantini, Giovanni and Fox, David J. (2015) The synthesis and STM/AFM imaging of ‘Olympicene’ benzo[cd]pyrenes. Chemistry - A European Journal, 21 (5). pp. 2011-2018. doi:10.1002/chem.201404877 ISSN 0947-6539.
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Official URL: http://dx.doi.org/10.1002/chem.201404877
Abstract
H-Benzo[cd]pyrene (‘Olympicene′) is a polyaromatic hydrocarbon and non-Kekulé fragment of graphene. A new synthetic method has been developed for the formation of 6H-benzo[cd]pyrene and related ketones including the first time isolation of the unstable alcohol 6H-benzo[cd]pyren-6-ol. Molecular imaging of the reaction products with scanning tunnelling microscopy (STM) and non-contact atomic force microscopy (NC-AFM) characterised the 6H-benzo[cd]pyrene as well as the previously intangible and significantly less stable 5H-benzo[cd]pyrene, the fully conjugated benzo[cd]pyrenyl radical and the ketones as oxidation products.
Item Type: | Journal Article | ||||||
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Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||
Journal or Publication Title: | Chemistry - A European Journal | ||||||
Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||||
ISSN: | 0947-6539 | ||||||
Official Date: | 26 January 2015 | ||||||
Dates: |
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Volume: | 21 | ||||||
Number: | 5 | ||||||
Page Range: | pp. 2011-2018 | ||||||
DOI: | 10.1002/chem.201404877 | ||||||
Status: | Peer Reviewed | ||||||
Publication Status: | Published | ||||||
Access rights to Published version: | Restricted or Subscription Access |
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