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Structured catalysts for biofuels transformation into syngas with active components based on perovskite and spinel oxides supported on Mg-doped alumina
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Sadykov, Vladislav, Pavlova, Svetlana, Smal, Ekaterina, Arapova, Marina, Simonov, Mikhail, Mezentseva, Natalia, Rogov, Vladimir, Glazneva, Tatiana, Lukashevich, Anton, Roger, Anne-Cecile, Parkhomenko, Ksenia, van Veen, André C. and Smorygo, Oleg (2017) Structured catalysts for biofuels transformation into syngas with active components based on perovskite and spinel oxides supported on Mg-doped alumina. Catalysis Today, 293-294 . pp. 176-185. doi:10.1016/j.cattod.2017.05.055
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Official URL: http://dx.doi.org/10.1016/j.cattod.2017.05.055
Abstract
For structured catalysts of biofuels transformation into syngas inexpensive and stable to sintering active components based upon Mg-doped γ-alumina with supported LaNi0.9Ru0.1O3 perovskite or MnCr2O4 spinel promoted by Ru + Ni were developed. Characterization of the surface features, reactivity, catalytic activity and routes of ethanol transformation on these catalysts demonstrated that suppression of support acidity, strong interaction of Ru-Ni alloy nanoparticles with manganese chromite layers on support and a high redox ability provide a high yield of syngas and stability to coking. The most promising active component (2 wt% Ni + 2 wt% Ru)/MnCr2O4/10 wt% MgO − γ-Al2O3 supported on microchannel heat-conducting CrAlO cermet plates demonstrated a high performance and stability to coking in the autothermal reforming of such reactive fuels as glycerol, anisol and turpentine oil.
| Item Type: | Journal Article | ||||||||
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| Divisions: | Faculty of Science > Engineering | ||||||||
| Journal or Publication Title: | Catalysis Today | ||||||||
| Publisher: | Elsevier BV | ||||||||
| ISSN: | 0920-5861 | ||||||||
| Official Date: | 15 September 2017 | ||||||||
| Dates: |
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| Volume: | 293-294 | ||||||||
| Page Range: | pp. 176-185 | ||||||||
| DOI: | 10.1016/j.cattod.2017.05.055 | ||||||||
| Status: | Peer Reviewed | ||||||||
| Publication Status: | Published | ||||||||
| Access rights to Published version: | Restricted or Subscription Access | ||||||||
| Funder: | Commission of the European Communities, Ministry of Education and Science of the Russian Federation |
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