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Chiral-at-metal organolanthanides: enantioselective aminoalkene hydroamination/cyclisation with non-cyclopentadienyls
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UNSPECIFIED (2003) Chiral-at-metal organolanthanides: enantioselective aminoalkene hydroamination/cyclisation with non-cyclopentadienyls. CHEMICAL COMMUNICATIONS (14). pp. 1770-1771. doi:10.1039/b305105f ISSN 1359-7345.
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Official URL: http://dx.doi.org/10.1039/b305105f
Abstract
Chiral non-racemic complexes [ML{N(SiMe2H)(2)}(thf)] ( M = Y, La, H2L = salicylaldimine ligands derived from 2,2'-diamino-6,6- dimethylbiphenyl) are found not to be effective catalysts for the intramolecular hydroamination of aminoalkenes, but new amino/phenoxide ligand designs without reducible functional groups led to long-lived and enantioselective catalysts.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | CHEMICAL COMMUNICATIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 1359-7345 | ||||
Official Date: | 2003 | ||||
Dates: |
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Number: | 14 | ||||
Number of Pages: | 2 | ||||
Page Range: | pp. 1770-1771 | ||||
DOI: | 10.1039/b305105f | ||||
Publication Status: | Published |
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