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One-pot sequence-controlled (SC) multiblock copolymers via copper-mediated polymerization
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Anastasaki, Athina, Whitfield, Richard, Nikolaou, Vasiliki, Truong, Nghia P., Jones, Glen R., Engelis, Nikolaos, Liarou, Evelina, Whittaker, Michael R. and Haddleton, David M. (2017) One-pot sequence-controlled (SC) multiblock copolymers via copper-mediated polymerization. In: Lutz, Jean‐François , (ed.) Sequence‐Controlled Polymers. Germany: Wiley-VCH Verlag GmbH & Co. KGaA, pp. 417-434. ISBN 9783527342372
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Official URL: https://doi.org/10.1002/9783527806096.ch14
Abstract
Over the past few years, the synthesis of sequence‐controlled (SC) multiblock copolymers has attracted considerable attention. Among the various polymerization techniques employed, copper mediated approaches have allowed access to both precisely controlled materials and also to fully optimized polymerization strategies. This provides additional access to the facile synthesis of less complex structures (e.g. diblocks and triblocks) that are routinely employed by the scientific community. This chapter aims to evaluate the main copper mediated radical polymerization techniques that can facilitate the synthesis of SC multiblock (≥ 5 blocks) copolymers and critically highlight the advancements of the field. Importantly, the potential and the limitations of each polymerization protocol will be critically evaluated and simplified with straightforward guidelines on the multiblock synthesis being further provided.
| Item Type: | Book Item | ||||
|---|---|---|---|---|---|
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
| SWORD Depositor: | Library Publications Router | ||||
| Journal or Publication Title: | Sequence-Controlled Polymers | ||||
| Publisher: | Wiley-VCH Verlag GmbH & Co. KGaA | ||||
| Place of Publication: | Germany | ||||
| ISBN: | 9783527342372 | ||||
| Book Title: | Sequence‐Controlled Polymers | ||||
| Editor: | Lutz, Jean‐François | ||||
| Official Date: | 4 December 2017 | ||||
| Dates: |
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| Page Range: | pp. 417-434 | ||||
| DOI: | 10.1002/9783527806096.ch14 | ||||
| Status: | Peer Reviewed | ||||
| Publication Status: | Published | ||||
| Reuse Statement (publisher, data, author rights): | ** From Crossref via Jisc Publications Router. | ||||
| Access rights to Published version: | Restricted or Subscription Access | ||||
| Date of first compliant deposit: | 18 October 2018 | ||||
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