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Characterisation of the interaction of glycine with Cu(100) and Cu(111)
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UNSPECIFIED (2003) Characterisation of the interaction of glycine with Cu(100) and Cu(111). Surface Science, 531 (3). pp. 304-318. doi:10.1016/S0039-6028(03)00541-7 ISSN 0039-6028.
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Official URL: http://dx.doi.org/10.1016/S0039-6028(03)00541-7
Abstract
Reflection-absorption infrared spectroscopy (RAIRS) has been used to characterise the interaction of standard and fully deuterated glycine with Cu(1 0 0) and Cu(1 1 1). RAIRS shows clearly that the surface interaction leads to formation of the adsorbed deprotonated glycinate (NH2CH2COO-) species, with some evidence for changes in orientation with coverage previously seen on Cu(1 1 0). Qualitative low energy electron diffraction observations were also conducted to characterise the long-range ordering, although effects of electron-beam-induced radiation damage limited the information obtained. Nevertheless, the results do suggest some subtle isotopic-mass-related structural variations. The results are discussed in the context of previously published scanning tunnelling microscopy and photoelectron diffraction measurements. (C) 2003 Elsevier Science B.V. All rights reserved.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry Q Science > QC Physics |
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Journal or Publication Title: | Surface Science | ||||
Publisher: | ELSEVIER SCIENCE BV | ||||
ISSN: | 0039-6028 | ||||
Official Date: | 1 June 2003 | ||||
Dates: |
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Volume: | 531 | ||||
Number: | 3 | ||||
Number of Pages: | 15 | ||||
Page Range: | pp. 304-318 | ||||
DOI: | 10.1016/S0039-6028(03)00541-7 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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