Template synthesis of an intermediate in silver salt metathesis using a calix[4]arene-based diphosphine ligand

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Abstract

The synthesis and solid-state characterisation of the heterobimetallic rhodium(III)/silver(I) complex [Rh(2,2’‑biphenyl)(CxP2)Cl]⊃Ag+ is described, where CxP2 is a trans-spanning calix[4]arene-based diphosphine and the silver cation is datively bound to the chloride ligand within the cavity of the macrocycle.

Item Type: Journal Article
Divisions: Faculty of Science, Engineering and Medicine > Science > Chemistry
Journal or Publication Title: Dalton Transactions
Publisher: Royal Society of Chemistry
ISSN: 1477-9226
Official Date: 28 April 2023
Dates:
Date
Event
28 April 2023
Published
3 April 2023
Available
31 March 2023
Accepted
Volume: 52
Number: 16
Page Range: pp. 5044-5046
DOI: 10.1039/D3DT00567D
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Open Access (Creative Commons open licence)
Date of first compliant deposit: 3 April 2023
Date of first compliant Open Access: 3 April 2023
URI: https://wrap.warwick.ac.uk/174839/

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