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Jump to: Advantage West Midlands (AWM) | Alexander von Humboldt-Stiftung | Centre national de la recherche scientifique (France) (CNRS) | Consejo nacional de ciencia y tecnología (México) | Engineering and Physical Sciences Research Council (EPSRC) | European Regional Development Fund (ERDF) | European Research Council (ERC) | Foundation for Research, Science & Technology (N.Z.) | France. Agence nationale de la recherche (ANR) | Galicia (Spain : Region). Xunta (XdG) | Herchel Smith Chair of Biochemistry Fund | Heriot-Watt University | Horizon 2020 (European Commission) (H2020) | Iraq. Wizārat al-Taʻlīm al-ʻĀlī wa-al-Baḥth al-ʻIlmī [Iraqi Ministry of Higher Education and Scientific Research] (MoHESR) | Leverhulme Trust (LT) | National Science Foundation (U.S.) (NSF) | Robert A. Welch Foundation | Royal Society (Great Britain) | Royal Society (Great Britain). University Research Fellowship | Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung [Swiss National Science Foundation] (SNF) | Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung [Swiss National Science Foundation] (SNSF) | University of Oxford | University of Oxford | University of Oxford. Oxford Supercomputing Centre | University of Warwick | University of Warwick Institute of Advanced Study Scholarship | Université de Toulouse | We thank the European Research Council (ERC, grant agreement 637313) and Royal Society (UF100592, UF150675, A.B.C.) for financial support. | École polytechnique fédérale de Lausanne [Swiss Federal Institute of Technology (Lausanne, Switzerland)] (EPFL) | École polytechnique fédérale de Lausanne [Swiss Federal Institute of Technology] (EPFL)
Number of items: 113.
Advantage West Midlands (AWM)
Emerson-King, Jack, Hauser, Simone A. and Chaplin, Adrian B. (2017) C–F bond activation of perfluorinated arenes by a bioxazoline-derived N-heterocyclic carbene. Organic and Biomolecular Chemistry, 15 (4). pp. 787-789. doi:10.1039/C6OB02556K ISSN 1477-0520.
Emerson-King, Jack, Knighton, Richard C., Gyton, Matthew R. and Chaplin, Adrian B. (2017) Rotaxane synthesis exploiting the M(i)/M(iii) redox couple. Dalton Transactions, 46 (35). pp. 11645-11655. doi:10.1039/c7dt02648j ISSN 1477-9226.
González-Sebastián, Lucer and Chaplin, Adrian B. (2017) Synthesis and complexes of imidazolinylidene-based CCC pincer ligands. Inorganica Chimica Acta, 460 . pp. 22-28. doi:10.1016/j.ica.2016.08.006 ISSN 0020-1693.
Hauser, Simone A., Emerson-King, Jack, Habershon, Scott and Chaplin, Adrian B. (2017) UV-light promoted C–H bond activation of benzene and fluorobenzenes by an iridium(i) pincer complex. Chemical Communications, 53 (26). pp. 3634-3636. doi:10.1039/C6CC09807J ISSN 1359-7345.
Patchett, Ruth and Chaplin, Adrian B. (2016) Coordination chemistry of a calix[4]arene-based NHC ligand : dinuclear complexes and comparison to IiPr2Me2. Dalton Transactions, 45 (21). pp. 8945-8955. doi:10.1039/c6dt01001f ISSN 1477-9226.
Alexander von Humboldt-Stiftung
Chaplin, Adrian B., Tonner, Ralf and Weller, Andrew S. (2010) Isolation of a low-coordinate rhodium phosphine complex formed by C−C bond activation of biphenylene. Organometallics, Vol.29 (No.12). pp. 2710-2714. doi:10.1021/om100149w ISSN 0276-7333.
Centre national de la recherche scientifique (France) (CNRS)
Stevens, Charlotte J., Dallanegra, Romaeo, Chaplin, Adrian B., Weller, Andrew S., Macgregor, Stuart A., Ward, B. (Bryan), McKay, D. (David), Alcaraz, Gilles and Sabo-Etienne, Sylviane (2011) [Ir(PCy(3))(2)(H)(2)(H(2)B-NMe(2))](+) as a latent source of aminoborane : probing the role of metal in the dehydrocoupling of H(3)B center dot NMe(2)H and retrodimerisation of [H(2)BNMe(2)](2). Chemistry: A European Journal, Vol.17 (No.10). pp. 3011-3020. doi:10.1002/chem.201002517 ISSN 0947-6539.
Alcaraz, Gilles, Chaplin, Adrian B., Stevens, Charlotte J., Clot, Eric, Vendier, Laure, Weller, Andrew S. and Sabo-Etienne, Sylviane (2010) Ruthenium, rhodium, and iridium bis(σ-B−H) diisopropylaminoborane complexes. Organometallics, Vol.29 (No.21). pp. 5591-5595. doi:10.1021/om1004995 ISSN 0276-7333.
Consejo nacional de ciencia y tecnología (México)
González-Sebastián, Lucer and Chaplin, Adrian B. (2017) Synthesis and complexes of imidazolinylidene-based CCC pincer ligands. Inorganica Chimica Acta, 460 . pp. 22-28. doi:10.1016/j.ica.2016.08.006 ISSN 0020-1693.
Engineering and Physical Sciences Research Council (EPSRC)
Emerson-King, Jack, Hauser, Simone A. and Chaplin, Adrian B. (2017) C–F bond activation of perfluorinated arenes by a bioxazoline-derived N-heterocyclic carbene. Organic and Biomolecular Chemistry, 15 (4). pp. 787-789. doi:10.1039/C6OB02556K ISSN 1477-0520.
Emerson-King, Jack, Knighton, Richard C., Gyton, Matthew R. and Chaplin, Adrian B. (2017) Rotaxane synthesis exploiting the M(i)/M(iii) redox couple. Dalton Transactions, 46 (35). pp. 11645-11655. doi:10.1039/c7dt02648j ISSN 1477-9226.
Knighton, Richard C. and Chaplin, Adrian B. (2017) Synthesis, structure and binding properties of a series of dissymmetric resorcin[4]arene-based cavitands. Tetrahedron, 73 (31). pp. 4591-4596. doi:10.1016/j.tet.2017.06.023 ISSN 0040-4020 .
Hauser, Simone A., Emerson-King, Jack, Habershon, Scott and Chaplin, Adrian B. (2017) UV-light promoted C–H bond activation of benzene and fluorobenzenes by an iridium(i) pincer complex. Chemical Communications, 53 (26). pp. 3634-3636. doi:10.1039/C6CC09807J ISSN 1359-7345.
Patchett, Ruth and Chaplin, Adrian B. (2016) Coordination chemistry of a calix[4]arene-based NHC ligand : dinuclear complexes and comparison to IiPr2Me2. Dalton Transactions, 45 (21). pp. 8945-8955. doi:10.1039/c6dt01001f ISSN 1477-9226.
Troadec, Thibault, Tan, Sze-yin, Wedge, Christopher, Rourke, Jonathan, Unwin, Patrick R. and Chaplin, Adrian B. (2016) One-electron oxidation of [M(PtBu3)2] (M=Pd, Pt) : isolation of monomeric [Pd(PtBu3)2]+and redox-promoted C−H bond cyclometalation. Angewandte Chemie International Edition, 55 (11). pp. 3754-3757. doi:10.1002/anie.201511467 ISSN 1433-7851.
Pike, Sebastian D., Pawley, R, Chaplin, Adrian B., Thompson, Amber L., Hooper, Joel A., Willis, Michael C. and Weller, Andrew S. (2011) Exploring (Ph2PCH2CH2)2E ligand space (E = O, S, PPh) in RhI alkene complexes as potential hydroacylation catalysts. European Journal of Inorganic Chemistry, Vol.2011 (No.36). pp. 5558-5565. doi:10.1002/ejic.201100958 ISSN 1434-1948.
Chaplin, Adrian B. and Weller, Andrew S. (2011) A rhodium(III) complex of the linear diborazine H3B·NMe2BH2·NMe2H : an intermediate in the dehydrocoupling of H3B·NMe2H. Acta Crystallographica. Section C: Crystal Structure Communications, Vol.67 (No.11). m355-m358. doi:10.1107/S0108270111043447 ISSN 0108-2701.
Chaplin, Adrian B. and Weller, Andrew S. (2011) [Rh{NC5H3-2,6-(CH2PtBu2)2}(PCy3)][BArF4] : a latent low-coordinate rhodium(I) PNP pincer compound. Organometallics, Vol.30 (No.16). pp. 4466-4469. doi:10.1021/om2004964 ISSN 0276-7333.
Pontiggia, Ashley J., Chaplin, Adrian B. and Weller, Andrew S. (2011) Cationic iridium complexes of the Xantphos ligand. Flexible coordination modes and the isolation of the hydride insertion product with an alkene. Journal of Organometallic Chemistry, Vol.696 (No.17). pp. 2870-2876. doi:10.1016/j.jorganchem.2011.01.036 ISSN 0022-328X.
Johnson, Heather C., Robertson, Alasdair P. M., Chaplin, Adrian B., Sewell, Laura J., Thompson, Amber L., Haddow, Mairi F., Manners, Ian and Weller, Andrew S. (2011) Catching the first oligomerization event in the catalytic formation of polyaminoboranes : H3B·NMeHBH2·NMeH2 bound to iridium. Journal of the American Chemical Society, Vol.133 (No.29). pp. 11076-11079. doi:10.1021/ja2040738 ISSN 0002-7863.
González-Rodríguez, Carlos, Pawley, Rebekah J., Chaplin, Adrian B., Thompson, Amber L., Weller, Andrew S. and Willis, Michael C. (2011) Rhodium-catalyzed branched-selective alkyne hydroacylation : a ligand-controlled regioselectivity switch. Angewandte Chemie International Edition, Vol.50 (No.22). pp. 5134-5138. doi:10.1002/anie.201100956 ISSN 1433-7851.
Stevens, Charlotte J., Dallanegra, Romaeo, Chaplin, Adrian B., Weller, Andrew S., Macgregor, Stuart A., Ward, B. (Bryan), McKay, D. (David), Alcaraz, Gilles and Sabo-Etienne, Sylviane (2011) [Ir(PCy(3))(2)(H)(2)(H(2)B-NMe(2))](+) as a latent source of aminoborane : probing the role of metal in the dehydrocoupling of H(3)B center dot NMe(2)H and retrodimerisation of [H(2)BNMe(2)](2). Chemistry: A European Journal, Vol.17 (No.10). pp. 3011-3020. doi:10.1002/chem.201002517 ISSN 0947-6539.
Chaplin, Adrian B. and Weller, Andrew S. (2010) [B(3,5-C6H3Cl2)4]- as a useful anion for organometallic chemistry. European Journal of Inorganic Chemistry, Vol.2010 (No.32). pp. 5124-5128. doi:10.1002/ejic.201000686 ISSN 1434-1948.
Sparkes, Hazel A., Chaplin, Adrian B., Weller, Andrew S. and Howard, J. A. K. (2010) Bond catastrophes in rhodium complexes : experimental charge-density studies of [Rh(C7H8)(PtBu3)Cl] and [Rh(C7H8)(PCy3)Cl]. Acta Crystallographica. Section B: Structural Science, Vol.66 (No.5). pp. 503-514. doi:10.1107/S0108768110031496 ISSN 0108-7681.
Sewell, Laura J., Chaplin, Adrian B., Abdallah, Joseph A. B. and Weller, Andrew S. (2010) Reversible C–H activation of a PtBuiBu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation. Dalton Transactions, Vol.39 (No.32). pp. 7437-7439. doi:10.1039/c0dt00449a ISSN 1477-9226.
Chaplin, Adrian B., Tonner, Ralf and Weller, Andrew S. (2010) Isolation of a low-coordinate rhodium phosphine complex formed by C−C bond activation of biphenylene. Organometallics, Vol.29 (No.12). pp. 2710-2714. doi:10.1021/om100149w ISSN 0276-7333.
Chaplin, Adrian B. and Weller, Andrew S. (2010) C−C bond activation of a cyclopropyl phosphine : isolation and reactivity of a tetrameric rhodacyclobutane. Organometallics, Vol.29 (No.10). pp. 2332-2342. doi:10.1021/om100105p ISSN 0276-7333.
Pawley, Rebekah J., Moxham, Gemma L., Dallanegra, Romaeo, Chaplin, Adrian B., Brayshaw, Simon K., Weller, Andrew S. and Willis, Michael C. (2010) Controlling selectivity in intermolecular alkene or aldehyde hydroacylation reactions catalyzed by {Rh(L2)}+ fragments. Organometallics, Vol.29 (No.7). pp. 1717-1728. doi:10.1021/om9011104 ISSN 0276-7333.
Chaplin, Adrian B. and Weller, Andrew S. (2010) Amine− and dimeric amino−borane complexes of the {Rh(PiPr3)2}+ fragment and their relevance to the transition-metal-mediated dehydrocoupling of amine−boranes. Inorganic Chemistry, Vol.49 (No.3). pp. 1111-1121. doi:10.1021/ic9020542 ISSN 0020-1669.
Hiney, Rachel M., Chaplin, Adrian B., Harmer, Jeffrey, Green, Jennifer C. and Weller, Andrew S. (2010) Using EPR to follow reversible dihydrogen addition to paramagnetic clusters of high hydride count : [Rh6(PCy3)6H12]+ and [Rh6(PCy3)6H14]+. Dalton Transactions, Vol.39 (No.7). pp. 1726-1733. doi:10.1039/b919209c ISSN 1477-9226.
Douglas, Thomas M., Chaplin, Adrian B., Weller, Andrew S., Yang, Xinzheng and Hall, Michael B. (2009) Monomeric and oligomeric amine−borane σ-complexes of rhodium. Intermediates in the catalytic dehydrogenation of amine−boranes. Journal of the American Chemical Society, Vol.131 (No.42). pp. 15440-15456. doi:10.1021/ja906070r ISSN 0002-7863.
Dallanegra, Romaeo, Chaplin, Adrian B. and Weller, Andrew S. (2009) Bis(σ-amine-borane) complexes : an unusual binding mode at a transition-metal center. Angewandte Chemie International Edition, Vol.48 (No.37). pp. 6875-6878. doi:10.1002/anie.200903121 ISSN 1433-7851.
Tang, Christina Y., Smith, W. (William), Vidovic, Dragoslav, Thompson, Amber L., Chaplin, Adrian B. and Aldridge, S. (Simon) (2009) Sterically encumbered iridium bis(N-heterocyclic carbene) systems : multiple C−H activation processes and isomeric normal/abnormal carbene complexes. Organometallics, Vol.28 (No.10). pp. 3059-3066. doi:10.1021/om9000082 ISSN 0276-7333.
Chaplin, Adrian B. and Weller, Andrew S. (2009) B-H activation at a rhodium(I) center : isolation of a bimetallic complex relevant to the transition-metal-catalyzed dehydrocoupling of amine-boranes. Angewandte Chemie International Edition, Vol.49 (No.3). pp. 581-584. doi:10.1002/anie.200905185 ISSN 1433-7851.
Douglas, Thomas M., Chaplin, Adrian B. and Weller, Andrew S. (2008) Amine-borane σ-complexes of rhodium. Relevance to the catalytic dehydrogenation of amine-boranes. Journal of the American Chemical Society, Vol.130 (No.44). pp. 14432-14433. doi:10.1021/ja806582n ISSN 0002-7863.
Douglas, Thomas M., Chaplin, Adrian B. and Weller, Andrew S. (2008) Dihydrogen loss from a 14-electron rhodium(III) bis-phosphine dihydride to give a rhodium(I) complex that undergoes oxidative addition with aryl chlorides. Organometallics, Vol.27 (No.13). pp. 2918-2921. doi:10.1021/om800373d ISSN 0276-7333.
European Regional Development Fund (ERDF)
Emerson-King, Jack, Hauser, Simone A. and Chaplin, Adrian B. (2017) C–F bond activation of perfluorinated arenes by a bioxazoline-derived N-heterocyclic carbene. Organic and Biomolecular Chemistry, 15 (4). pp. 787-789. doi:10.1039/C6OB02556K ISSN 1477-0520.
Emerson-King, Jack, Knighton, Richard C., Gyton, Matthew R. and Chaplin, Adrian B. (2017) Rotaxane synthesis exploiting the M(i)/M(iii) redox couple. Dalton Transactions, 46 (35). pp. 11645-11655. doi:10.1039/c7dt02648j ISSN 1477-9226.
González-Sebastián, Lucer and Chaplin, Adrian B. (2017) Synthesis and complexes of imidazolinylidene-based CCC pincer ligands. Inorganica Chimica Acta, 460 . pp. 22-28. doi:10.1016/j.ica.2016.08.006 ISSN 0020-1693.
Hauser, Simone A., Emerson-King, Jack, Habershon, Scott and Chaplin, Adrian B. (2017) UV-light promoted C–H bond activation of benzene and fluorobenzenes by an iridium(i) pincer complex. Chemical Communications, 53 (26). pp. 3634-3636. doi:10.1039/C6CC09807J ISSN 1359-7345.
Patchett, Ruth and Chaplin, Adrian B. (2016) Coordination chemistry of a calix[4]arene-based NHC ligand : dinuclear complexes and comparison to IiPr2Me2. Dalton Transactions, 45 (21). pp. 8945-8955. doi:10.1039/c6dt01001f ISSN 1477-9226.
European Research Council (ERC)
Apps, Samantha L., Alflatt, Rhiannon E., Leforestier, Baptiste, Storey, Caroline M. and Chaplin, Adrian B. (2018) Divergent stereoisomers of molybdenum carbonyl complexes of NHC-based pincer ligands. Polyhedron, 143 . pp. 57-61. doi:10.1016/j.poly.2017.08.001 ISSN 0277-5387.
Emerson-King, Jack, Knighton, Richard C., Gyton, Matthew R. and Chaplin, Adrian B. (2017) Rotaxane synthesis exploiting the M(i)/M(iii) redox couple. Dalton Transactions, 46 (35). pp. 11645-11655. doi:10.1039/c7dt02648j ISSN 1477-9226.
Pike, Sebastian D., Crimmin, Mark R. and Chaplin, Adrian B. (2017) Organometallic chemistry using partially fluorinated benzenes. Chemical Communications, 53 (26). pp. 3615-3633. doi:10.1039/C6CC09575E ISSN 1359-7345.
Andrew, Rhiann, Storey, Caroline M. and Chaplin, Adrian B. (2016) Well-defined coinage metal transfer agents for the synthesis of NHC-based nickel, rhodium and palladium macrocycles. Dalton Transactions, 45 (21). pp. 8937-8944. doi:10.1039/c6dt01263a ISSN 1477-9226.
Foundation for Research, Science & Technology (N.Z.)
Chaplin, Adrian B. and Dyson, Paul J. (2011) Influence of arene dissociation and phosphine coordination on the catalytic activity of [RuCl(κ2-triphos)(p-cymene)]PF6. Journal of Organometallic Chemistry, Vol.696 (No.13). pp. 2485-2490. doi:10.1016/j.jorganchem.2011.02.022 ISSN 0022-328X.
France. Agence nationale de la recherche (ANR)
Stevens, Charlotte J., Dallanegra, Romaeo, Chaplin, Adrian B., Weller, Andrew S., Macgregor, Stuart A., Ward, B. (Bryan), McKay, D. (David), Alcaraz, Gilles and Sabo-Etienne, Sylviane (2011) [Ir(PCy(3))(2)(H)(2)(H(2)B-NMe(2))](+) as a latent source of aminoborane : probing the role of metal in the dehydrocoupling of H(3)B center dot NMe(2)H and retrodimerisation of [H(2)BNMe(2)](2). Chemistry: A European Journal, Vol.17 (No.10). pp. 3011-3020. doi:10.1002/chem.201002517 ISSN 0947-6539.
Alcaraz, Gilles, Chaplin, Adrian B., Stevens, Charlotte J., Clot, Eric, Vendier, Laure, Weller, Andrew S. and Sabo-Etienne, Sylviane (2010) Ruthenium, rhodium, and iridium bis(σ-B−H) diisopropylaminoborane complexes. Organometallics, Vol.29 (No.21). pp. 5591-5595. doi:10.1021/om1004995 ISSN 0276-7333.
Galicia (Spain : Region). Xunta (XdG)
González-Rodríguez, Carlos, Pawley, Rebekah J., Chaplin, Adrian B., Thompson, Amber L., Weller, Andrew S. and Willis, Michael C. (2011) Rhodium-catalyzed branched-selective alkyne hydroacylation : a ligand-controlled regioselectivity switch. Angewandte Chemie International Edition, Vol.50 (No.22). pp. 5134-5138. doi:10.1002/anie.201100956 ISSN 1433-7851.
Herchel Smith Chair of Biochemistry Fund
Pike, Sebastian D., Crimmin, Mark R. and Chaplin, Adrian B. (2017) Organometallic chemistry using partially fluorinated benzenes. Chemical Communications, 53 (26). pp. 3615-3633. doi:10.1039/C6CC09575E ISSN 1359-7345.
Heriot-Watt University
Stevens, Charlotte J., Dallanegra, Romaeo, Chaplin, Adrian B., Weller, Andrew S., Macgregor, Stuart A., Ward, B. (Bryan), McKay, D. (David), Alcaraz, Gilles and Sabo-Etienne, Sylviane (2011) [Ir(PCy(3))(2)(H)(2)(H(2)B-NMe(2))](+) as a latent source of aminoborane : probing the role of metal in the dehydrocoupling of H(3)B center dot NMe(2)H and retrodimerisation of [H(2)BNMe(2)](2). Chemistry: A European Journal, Vol.17 (No.10). pp. 3011-3020. doi:10.1002/chem.201002517 ISSN 0947-6539.
Horizon 2020 (European Commission) (H2020)
Emerson-King, Jack, Knighton, Richard C., Gyton, Matthew R. and Chaplin, Adrian B. (2017) Rotaxane synthesis exploiting the M(i)/M(iii) redox couple. Dalton Transactions, 46 (35). pp. 11645-11655. doi:10.1039/c7dt02648j ISSN 1477-9226.
Iraq. Wizārat al-Taʻlīm al-ʻĀlī wa-al-Baḥth al-ʻIlmī [Iraqi Ministry of Higher Education and Scientific Research] (MoHESR)
Woolf, Anthony, Alibadi, Muhsen A. M., Chaplin, Adrian B., McGrady, J. E. (John E.) and Weller, Andrew S. (2011) {Rh(PiBu3)2}+ fragments ligated to arenes : from benzene to polyaromatic hydrocarbons, part II - computational analysis of pathways for haptotropic migration. European Journal of Inorganic Chemistry, Vol.2011 (No.10). pp. 1626-1634. doi:10.1002/ejic.201001264 ISSN 1434-1948.
Leverhulme Trust (LT)
Emerson-King, Jack, Knighton, Richard C., Gyton, Matthew R. and Chaplin, Adrian B. (2017) Rotaxane synthesis exploiting the M(i)/M(iii) redox couple. Dalton Transactions, 46 (35). pp. 11645-11655. doi:10.1039/c7dt02648j ISSN 1477-9226.
Troadec, Thibault, Tan, Sze-yin, Wedge, Christopher, Rourke, Jonathan, Unwin, Patrick R. and Chaplin, Adrian B. (2016) One-electron oxidation of [M(PtBu3)2] (M=Pd, Pt) : isolation of monomeric [Pd(PtBu3)2]+and redox-promoted C−H bond cyclometalation. Angewandte Chemie International Edition, 55 (11). pp. 3754-3757. doi:10.1002/anie.201511467 ISSN 1433-7851.
National Science Foundation (U.S.) (NSF)
Douglas, Thomas M., Chaplin, Adrian B., Weller, Andrew S., Yang, Xinzheng and Hall, Michael B. (2009) Monomeric and oligomeric amine−borane σ-complexes of rhodium. Intermediates in the catalytic dehydrogenation of amine−boranes. Journal of the American Chemical Society, Vol.131 (No.42). pp. 15440-15456. doi:10.1021/ja906070r ISSN 0002-7863.
Robert A. Welch Foundation
Douglas, Thomas M., Chaplin, Adrian B., Weller, Andrew S., Yang, Xinzheng and Hall, Michael B. (2009) Monomeric and oligomeric amine−borane σ-complexes of rhodium. Intermediates in the catalytic dehydrogenation of amine−boranes. Journal of the American Chemical Society, Vol.131 (No.42). pp. 15440-15456. doi:10.1021/ja906070r ISSN 0002-7863.
Royal Society (Great Britain)
Apps, Samantha L., Alflatt, Rhiannon E., Leforestier, Baptiste, Storey, Caroline M. and Chaplin, Adrian B. (2018) Divergent stereoisomers of molybdenum carbonyl complexes of NHC-based pincer ligands. Polyhedron, 143 . pp. 57-61. doi:10.1016/j.poly.2017.08.001 ISSN 0277-5387.
Emerson-King, Jack, Hauser, Simone A. and Chaplin, Adrian B. (2017) C–F bond activation of perfluorinated arenes by a bioxazoline-derived N-heterocyclic carbene. Organic and Biomolecular Chemistry, 15 (4). pp. 787-789. doi:10.1039/C6OB02556K ISSN 1477-0520.
Emerson-King, Jack, Knighton, Richard C., Gyton, Matthew R. and Chaplin, Adrian B. (2017) Rotaxane synthesis exploiting the M(i)/M(iii) redox couple. Dalton Transactions, 46 (35). pp. 11645-11655. doi:10.1039/c7dt02648j ISSN 1477-9226.
González-Sebastián, Lucer and Chaplin, Adrian B. (2017) Synthesis and complexes of imidazolinylidene-based CCC pincer ligands. Inorganica Chimica Acta, 460 . pp. 22-28. doi:10.1016/j.ica.2016.08.006 ISSN 0020-1693.
Pike, Sebastian D., Crimmin, Mark R. and Chaplin, Adrian B. (2017) Organometallic chemistry using partially fluorinated benzenes. Chemical Communications, 53 (26). pp. 3615-3633. doi:10.1039/C6CC09575E ISSN 1359-7345.
Hauser, Simone A., Emerson-King, Jack, Habershon, Scott and Chaplin, Adrian B. (2017) UV-light promoted C–H bond activation of benzene and fluorobenzenes by an iridium(i) pincer complex. Chemical Communications, 53 (26). pp. 3634-3636. doi:10.1039/C6CC09807J ISSN 1359-7345.
Patchett, Ruth and Chaplin, Adrian B. (2016) Coordination chemistry of a calix[4]arene-based NHC ligand : dinuclear complexes and comparison to IiPr2Me2. Dalton Transactions, 45 (21). pp. 8945-8955. doi:10.1039/c6dt01001f ISSN 1477-9226.
Andrew, Rhiann, Storey, Caroline M. and Chaplin, Adrian B. (2016) Well-defined coinage metal transfer agents for the synthesis of NHC-based nickel, rhodium and palladium macrocycles. Dalton Transactions, 45 (21). pp. 8937-8944. doi:10.1039/c6dt01263a ISSN 1477-9226.
Troadec, Thibault, Tan, Sze-yin, Wedge, Christopher, Rourke, Jonathan, Unwin, Patrick R. and Chaplin, Adrian B. (2016) One-electron oxidation of [M(PtBu3)2] (M=Pd, Pt) : isolation of monomeric [Pd(PtBu3)2]+and redox-promoted C−H bond cyclometalation. Angewandte Chemie International Edition, 55 (11). pp. 3754-3757. doi:10.1002/anie.201511467 ISSN 1433-7851.
Luy, Jan-Niclas, Hauser, Simone A., Chaplin, Adrian B. and Tonner, Ralf (2015) Rhodium(I) and Iridium(I) complexes of the conformationally rigid IBioxMe4Ligand : computational and experimental studies of unusually tilted NHC coordination geometries. Organometallics, 34 (20). pp. 5099-5112. doi:10.1021/acs.organomet.5b00692 ISSN 0276-7333.
Hauser, Simone A., Tonner, Ralf and Chaplin, Adrian B. (2015) Iridium complexes of the conformationally rigid IBioxMe4Ligand : hydride complexes and dehydrogenation of cyclooctene. Organometallics, 34 (17). pp. 4419-4427. doi:10.1021/acs.organomet.5b00658 ISSN 0276-7333.
Hauser, Simone A., Prokes, Ivan and Chaplin, Adrian B. (2015) Low-coordinate iridium NHC complexes derived from selective and reversible C–H bond activation of fluoroarenes. Chemical Communications, 51 (21). pp. 4425-4428. doi:10.1039/c5cc00529a ISSN 1359-7345.
Andrew, Rhiann and Chaplin, Adrian B. (2014) Synthesis, structure and dynamics of NHC-based palladium macrocycles. Dalton Transactions, Volume 43 (Number). pp. 1413-1423. doi:10.1039/c3dt52578c ISSN 1477-9226.
Royal Society (Great Britain). University Research Fellowship
Knighton, Richard C. and Chaplin, Adrian B. (2017) Synthesis, structure and binding properties of a series of dissymmetric resorcin[4]arene-based cavitands. Tetrahedron, 73 (31). pp. 4591-4596. doi:10.1016/j.tet.2017.06.023 ISSN 0040-4020 .
Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung [Swiss National Science Foundation] (SNF)
Chaplin, Adrian B. and Dyson, Paul J. (2011) Influence of arene dissociation and phosphine coordination on the catalytic activity of [RuCl(κ2-triphos)(p-cymene)]PF6. Journal of Organometallic Chemistry, Vol.696 (No.13). pp. 2485-2490. doi:10.1016/j.jorganchem.2011.02.022 ISSN 0022-328X.
Chaplin, Adrian B., Béni, Zoltán, Hartinger, Christian G., Hamidane, Hisham Ben, Phillips, Andrew D., Scopelliti, Rosario and Dyson, Paul J. (2008) Linked metal-cluster systems : isolation and characterisation of {anti-[(p-cymene)RuCl]-μ-[κ 2-P,P′;κ 1-P′′-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2. Journal of Cluster Science, Vol.19 (No.1). pp. 295-309. doi:10.1007/s10876-007-0175-0 ISSN 1040-7278.
Chaplin, Adrian B. and Dyson, Paul J. (2008) Reactivity and catalytic activity of a robust ruthenium(II)−triphos complex. Inorganic Chemistry, Vol.47 (No.1). pp. 381-390. doi:10.1021/ic701773a ISSN 0020-1669.
Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung [Swiss National Science Foundation] (SNSF)
Emerson-King, Jack, Hauser, Simone A. and Chaplin, Adrian B. (2017) C–F bond activation of perfluorinated arenes by a bioxazoline-derived N-heterocyclic carbene. Organic and Biomolecular Chemistry, 15 (4). pp. 787-789. doi:10.1039/C6OB02556K ISSN 1477-0520.
Hauser, Simone A., Emerson-King, Jack, Habershon, Scott and Chaplin, Adrian B. (2017) UV-light promoted C–H bond activation of benzene and fluorobenzenes by an iridium(i) pincer complex. Chemical Communications, 53 (26). pp. 3634-3636. doi:10.1039/C6CC09807J ISSN 1359-7345.
Luy, Jan-Niclas, Hauser, Simone A., Chaplin, Adrian B. and Tonner, Ralf (2015) Rhodium(I) and Iridium(I) complexes of the conformationally rigid IBioxMe4Ligand : computational and experimental studies of unusually tilted NHC coordination geometries. Organometallics, 34 (20). pp. 5099-5112. doi:10.1021/acs.organomet.5b00692 ISSN 0276-7333.
Hauser, Simone A., Tonner, Ralf and Chaplin, Adrian B. (2015) Iridium complexes of the conformationally rigid IBioxMe4Ligand : hydride complexes and dehydrogenation of cyclooctene. Organometallics, 34 (17). pp. 4419-4427. doi:10.1021/acs.organomet.5b00658 ISSN 0276-7333.
Hauser, Simone A., Prokes, Ivan and Chaplin, Adrian B. (2015) Low-coordinate iridium NHC complexes derived from selective and reversible C–H bond activation of fluoroarenes. Chemical Communications, 51 (21). pp. 4425-4428. doi:10.1039/c5cc00529a ISSN 1359-7345.
University of Oxford
Pike, Sebastian D., Pawley, R, Chaplin, Adrian B., Thompson, Amber L., Hooper, Joel A., Willis, Michael C. and Weller, Andrew S. (2011) Exploring (Ph2PCH2CH2)2E ligand space (E = O, S, PPh) in RhI alkene complexes as potential hydroacylation catalysts. European Journal of Inorganic Chemistry, Vol.2011 (No.36). pp. 5558-5565. doi:10.1002/ejic.201100958 ISSN 1434-1948.
Chaplin, Adrian B. and Weller, Andrew S. (2011) A rhodium(III) complex of the linear diborazine H3B·NMe2BH2·NMe2H : an intermediate in the dehydrocoupling of H3B·NMe2H. Acta Crystallographica. Section C: Crystal Structure Communications, Vol.67 (No.11). m355-m358. doi:10.1107/S0108270111043447 ISSN 0108-2701.
Pontiggia, Ashley J., Chaplin, Adrian B. and Weller, Andrew S. (2011) Cationic iridium complexes of the Xantphos ligand. Flexible coordination modes and the isolation of the hydride insertion product with an alkene. Journal of Organometallic Chemistry, Vol.696 (No.17). pp. 2870-2876. doi:10.1016/j.jorganchem.2011.01.036 ISSN 0022-328X.
Johnson, Heather C., Robertson, Alasdair P. M., Chaplin, Adrian B., Sewell, Laura J., Thompson, Amber L., Haddow, Mairi F., Manners, Ian and Weller, Andrew S. (2011) Catching the first oligomerization event in the catalytic formation of polyaminoboranes : H3B·NMeHBH2·NMeH2 bound to iridium. Journal of the American Chemical Society, Vol.133 (No.29). pp. 11076-11079. doi:10.1021/ja2040738 ISSN 0002-7863.
Stevens, Charlotte J., Dallanegra, Romaeo, Chaplin, Adrian B., Weller, Andrew S., Macgregor, Stuart A., Ward, B. (Bryan), McKay, D. (David), Alcaraz, Gilles and Sabo-Etienne, Sylviane (2011) [Ir(PCy(3))(2)(H)(2)(H(2)B-NMe(2))](+) as a latent source of aminoborane : probing the role of metal in the dehydrocoupling of H(3)B center dot NMe(2)H and retrodimerisation of [H(2)BNMe(2)](2). Chemistry: A European Journal, Vol.17 (No.10). pp. 3011-3020. doi:10.1002/chem.201002517 ISSN 0947-6539.
Chaplin, Adrian B. and Weller, Andrew S. (2010) [B(3,5-C6H3Cl2)4]- as a useful anion for organometallic chemistry. European Journal of Inorganic Chemistry, Vol.2010 (No.32). pp. 5124-5128. doi:10.1002/ejic.201000686 ISSN 1434-1948.
Chaplin, Adrian B., Tonner, Ralf and Weller, Andrew S. (2010) Isolation of a low-coordinate rhodium phosphine complex formed by C−C bond activation of biphenylene. Organometallics, Vol.29 (No.12). pp. 2710-2714. doi:10.1021/om100149w ISSN 0276-7333.
Chaplin, Adrian B. and Weller, Andrew S. (2010) C−C bond activation of a cyclopropyl phosphine : isolation and reactivity of a tetrameric rhodacyclobutane. Organometallics, Vol.29 (No.10). pp. 2332-2342. doi:10.1021/om100105p ISSN 0276-7333.
Pawley, Rebekah J., Moxham, Gemma L., Dallanegra, Romaeo, Chaplin, Adrian B., Brayshaw, Simon K., Weller, Andrew S. and Willis, Michael C. (2010) Controlling selectivity in intermolecular alkene or aldehyde hydroacylation reactions catalyzed by {Rh(L2)}+ fragments. Organometallics, Vol.29 (No.7). pp. 1717-1728. doi:10.1021/om9011104 ISSN 0276-7333.
Chaplin, Adrian B. and Weller, Andrew S. (2010) Amine− and dimeric amino−borane complexes of the {Rh(PiPr3)2}+ fragment and their relevance to the transition-metal-mediated dehydrocoupling of amine−boranes. Inorganic Chemistry, Vol.49 (No.3). pp. 1111-1121. doi:10.1021/ic9020542 ISSN 0020-1669.
Hiney, Rachel M., Chaplin, Adrian B., Harmer, Jeffrey, Green, Jennifer C. and Weller, Andrew S. (2010) Using EPR to follow reversible dihydrogen addition to paramagnetic clusters of high hydride count : [Rh6(PCy3)6H12]+ and [Rh6(PCy3)6H14]+. Dalton Transactions, Vol.39 (No.7). pp. 1726-1733. doi:10.1039/b919209c ISSN 1477-9226.
Dallanegra, Romaeo, Chaplin, Adrian B. and Weller, Andrew S. (2009) Bis(σ-amine-borane) complexes : an unusual binding mode at a transition-metal center. Angewandte Chemie International Edition, Vol.48 (No.37). pp. 6875-6878. doi:10.1002/anie.200903121 ISSN 1433-7851.
Douglas, Thomas M., Chaplin, Adrian B. and Weller, Andrew S. (2008) Dihydrogen loss from a 14-electron rhodium(III) bis-phosphine dihydride to give a rhodium(I) complex that undergoes oxidative addition with aryl chlorides. Organometallics, Vol.27 (No.13). pp. 2918-2921. doi:10.1021/om800373d ISSN 0276-7333.
University of Oxford
Alcaraz, Gilles, Chaplin, Adrian B., Stevens, Charlotte J., Clot, Eric, Vendier, Laure, Weller, Andrew S. and Sabo-Etienne, Sylviane (2010) Ruthenium, rhodium, and iridium bis(σ-B−H) diisopropylaminoborane complexes. Organometallics, Vol.29 (No.21). pp. 5591-5595. doi:10.1021/om1004995 ISSN 0276-7333.
Sewell, Laura J., Chaplin, Adrian B., Abdallah, Joseph A. B. and Weller, Andrew S. (2010) Reversible C–H activation of a PtBuiBu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation. Dalton Transactions, Vol.39 (No.32). pp. 7437-7439. doi:10.1039/c0dt00449a ISSN 1477-9226.
Douglas, Thomas M., Chaplin, Adrian B., Weller, Andrew S., Yang, Xinzheng and Hall, Michael B. (2009) Monomeric and oligomeric amine−borane σ-complexes of rhodium. Intermediates in the catalytic dehydrogenation of amine−boranes. Journal of the American Chemical Society, Vol.131 (No.42). pp. 15440-15456. doi:10.1021/ja906070r ISSN 0002-7863.
University of Oxford. Oxford Supercomputing Centre
Hiney, Rachel M., Chaplin, Adrian B., Harmer, Jeffrey, Green, Jennifer C. and Weller, Andrew S. (2010) Using EPR to follow reversible dihydrogen addition to paramagnetic clusters of high hydride count : [Rh6(PCy3)6H12]+ and [Rh6(PCy3)6H14]+. Dalton Transactions, Vol.39 (No.7). pp. 1726-1733. doi:10.1039/b919209c ISSN 1477-9226.
University of Warwick
Apps, Samantha L., Alflatt, Rhiannon E., Leforestier, Baptiste, Storey, Caroline M. and Chaplin, Adrian B. (2018) Divergent stereoisomers of molybdenum carbonyl complexes of NHC-based pincer ligands. Polyhedron, 143 . pp. 57-61. doi:10.1016/j.poly.2017.08.001 ISSN 0277-5387.
Emerson-King, Jack, Hauser, Simone A. and Chaplin, Adrian B. (2017) C–F bond activation of perfluorinated arenes by a bioxazoline-derived N-heterocyclic carbene. Organic and Biomolecular Chemistry, 15 (4). pp. 787-789. doi:10.1039/C6OB02556K ISSN 1477-0520.
González-Sebastián, Lucer and Chaplin, Adrian B. (2017) Synthesis and complexes of imidazolinylidene-based CCC pincer ligands. Inorganica Chimica Acta, 460 . pp. 22-28. doi:10.1016/j.ica.2016.08.006 ISSN 0020-1693.
Hauser, Simone A., Emerson-King, Jack, Habershon, Scott and Chaplin, Adrian B. (2017) UV-light promoted C–H bond activation of benzene and fluorobenzenes by an iridium(i) pincer complex. Chemical Communications, 53 (26). pp. 3634-3636. doi:10.1039/C6CC09807J ISSN 1359-7345.
Patchett, Ruth and Chaplin, Adrian B. (2016) Coordination chemistry of a calix[4]arene-based NHC ligand : dinuclear complexes and comparison to IiPr2Me2. Dalton Transactions, 45 (21). pp. 8945-8955. doi:10.1039/c6dt01001f ISSN 1477-9226.
Andrew, Rhiann, Storey, Caroline M. and Chaplin, Adrian B. (2016) Well-defined coinage metal transfer agents for the synthesis of NHC-based nickel, rhodium and palladium macrocycles. Dalton Transactions, 45 (21). pp. 8937-8944. doi:10.1039/c6dt01263a ISSN 1477-9226.
Hauser, Simone A., Tonner, Ralf and Chaplin, Adrian B. (2015) Iridium complexes of the conformationally rigid IBioxMe4Ligand : hydride complexes and dehydrogenation of cyclooctene. Organometallics, 34 (17). pp. 4419-4427. doi:10.1021/acs.organomet.5b00658 ISSN 0276-7333.
Hauser, Simone A., Prokes, Ivan and Chaplin, Adrian B. (2015) Low-coordinate iridium NHC complexes derived from selective and reversible C–H bond activation of fluoroarenes. Chemical Communications, 51 (21). pp. 4425-4428. doi:10.1039/c5cc00529a ISSN 1359-7345.
Andrew, Rhiann and Chaplin, Adrian B. (2014) Synthesis, structure and dynamics of NHC-based palladium macrocycles. Dalton Transactions, Volume 43 (Number). pp. 1413-1423. doi:10.1039/c3dt52578c ISSN 1477-9226.
University of Warwick Institute of Advanced Study Scholarship
Luy, Jan-Niclas, Hauser, Simone A., Chaplin, Adrian B. and Tonner, Ralf (2015) Rhodium(I) and Iridium(I) complexes of the conformationally rigid IBioxMe4Ligand : computational and experimental studies of unusually tilted NHC coordination geometries. Organometallics, 34 (20). pp. 5099-5112. doi:10.1021/acs.organomet.5b00692 ISSN 0276-7333.
Hauser, Simone A., Tonner, Ralf and Chaplin, Adrian B. (2015) Iridium complexes of the conformationally rigid IBioxMe4Ligand : hydride complexes and dehydrogenation of cyclooctene. Organometallics, 34 (17). pp. 4419-4427. doi:10.1021/acs.organomet.5b00658 ISSN 0276-7333.
Université de Toulouse
Stevens, Charlotte J., Dallanegra, Romaeo, Chaplin, Adrian B., Weller, Andrew S., Macgregor, Stuart A., Ward, B. (Bryan), McKay, D. (David), Alcaraz, Gilles and Sabo-Etienne, Sylviane (2011) [Ir(PCy(3))(2)(H)(2)(H(2)B-NMe(2))](+) as a latent source of aminoborane : probing the role of metal in the dehydrocoupling of H(3)B center dot NMe(2)H and retrodimerisation of [H(2)BNMe(2)](2). Chemistry: A European Journal, Vol.17 (No.10). pp. 3011-3020. doi:10.1002/chem.201002517 ISSN 0947-6539.
Alcaraz, Gilles, Chaplin, Adrian B., Stevens, Charlotte J., Clot, Eric, Vendier, Laure, Weller, Andrew S. and Sabo-Etienne, Sylviane (2010) Ruthenium, rhodium, and iridium bis(σ-B−H) diisopropylaminoborane complexes. Organometallics, Vol.29 (No.21). pp. 5591-5595. doi:10.1021/om1004995 ISSN 0276-7333.
We thank the European Research Council (ERC, grant agreement 637313) and Royal Society (UF100592, UF150675, A.B.C.) for financial support.
Hood, Thomas M., Lau, S. and Chaplin, Adrian B. (2024) Capture of mechanically interlocked molecules using rhodium-mediated terminal alkyne dimerisation. RSC Advances , 14 (11). pp. 7740-7744. doi:10.1039/D4RA00566J ISSN 2046-2069.
École polytechnique fédérale de Lausanne [Swiss Federal Institute of Technology (Lausanne, Switzerland)] (EPFL)
Chaplin, Adrian B. and Dyson, Paul J. (2011) Influence of arene dissociation and phosphine coordination on the catalytic activity of [RuCl(κ2-triphos)(p-cymene)]PF6. Journal of Organometallic Chemistry, Vol.696 (No.13). pp. 2485-2490. doi:10.1016/j.jorganchem.2011.02.022 ISSN 0022-328X.
Chaplin, Adrian B. and Dyson, Paul J. (2008) Reactivity and catalytic activity of a robust ruthenium(II)−triphos complex. Inorganic Chemistry, Vol.47 (No.1). pp. 381-390. doi:10.1021/ic701773a ISSN 0020-1669.
École polytechnique fédérale de Lausanne [Swiss Federal Institute of Technology] (EPFL)
Chaplin, Adrian B., Béni, Zoltán, Hartinger, Christian G., Hamidane, Hisham Ben, Phillips, Andrew D., Scopelliti, Rosario and Dyson, Paul J. (2008) Linked metal-cluster systems : isolation and characterisation of {anti-[(p-cymene)RuCl]-μ-[κ 2-P,P′;κ 1-P′′-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2. Journal of Cluster Science, Vol.19 (No.1). pp. 295-309. doi:10.1007/s10876-007-0175-0 ISSN 1040-7278.
This list was generated on Thu Mar 28 18:07:06 2024 GMT.