2022

Bugden, Frances E., Clarkson, Guy J. and Greenhalgh, Mark David (2022) Lithiation‐functionalisation of triazoles bearing electron‐withdrawing N‐substituents : challenges and solutions. European Journal of Organic Chemistry . doi:10.1002/ejoc.202201459 ISSN 1434-193X. (In Press)

Smith, Samuel M., Greenhalgh, Mark D., Feoktistova, Taisiia, Walden, Daniel M., Taylor, James E., Cordes, David B., Slawin, Alexandra M. Z., Cheong, Paul Ha‐Yeon and Smith, Andrew D. (2022) Scope, limitations and mechanistic analysis of the HyperBTM‐catalyzed acylative kinetic resolution of tertiary heterocyclic alcohols. European Journal of Organic Chemistry, 2022 (1). e00264. doi:10.1002/ejoc.202101111 ISSN 1434-193X.

2021

Arokianathar, Jude N., Hartley, Will C., McLaughlin, Calum, Greenhalgh, Mark D., Stead, Darren, Ng, Sean, Slawin, Alexandra M. Z. and Smith, Andrew D. (2021) Isothiourea-catalyzed enantioselective α-alkylation of esters via 1,6-conjugate addition to para-quinone methides. Molecules, 26 (21). 6333. doi:10.3390/molecules26216333 ISSN 1420-3049.

Brandolese, Arianna, Greenhalgh, Mark D., Desrues, Titouan, Liu, Xueyang, Qu, Shen, Bressy, Cyril and Smith, Andrew D. (2021) Horeau amplification in the sequential acylative kinetic resolution of (±)-1,2-diols and (±)-1,3-diols in flow. Organic & Biomolecular Chemistry, 19 (16). pp. 3620-3627. doi:10.1039/d1ob00304f ISSN 1477-0520.

2020

Smith, Andrew David, Zhang, Shuyue, Hartley, Will C., Greenhalgh, Mark D., Ng, Sean and Slawin, Alexandra M. Z. (2020) Isothiourea‐catalyzed synthesis of pyrrole‐ and indole‐functionalized tetrasubstituted pyridines. ChemCatChem, 12 (18). pp. 4522-4525. doi:10.1002/cctc.202000882 ISSN 1867-3880.

Qu, Shen, Smith, Sam, Laina, Victor, Neyyappadath, Rifahath M., Greenhalgh, Mark D. and Smith, Andrew David (2020) Isothiourea‐catalyzed acylative kinetic resolution of tertiary α‐Hydroxy esters. Angewandte Chemie International Edition, 59 (38). pp. 16572-16578. doi:10.1002/anie.202004354 ISSN 1433-7851.

Davies, Alyn T., Greenhalgh, Mark D., Slawin, Alexandra M Z and Smith, Andrew D. (2020) NHC-catalyzed enantioselective synthesis of β-trifluoromethyl-β-hydroxyamides. Beilstein Journal of Organic Chemistry, 16 . pp. 1572-1578. doi:10.3762/bjoc.16.129 ISSN 1860-5397.

Neate, Peter G. N., Greenhalgh, Mark D., Brennessel, William, Thomas, Stephen M. and Neidig, Michael (2020) TMEDA in iron‐catalyzed hydromagnesiation : formation of iron(II)‐alkyl species for controlled reduction to alkene‐stabilized iron(0). Angewandte Chemie International Edition . doi:10.1002/anie.202006639 ISSN 1433-7851.

2019

Barrios Antúnez, Diego-Javier, Greenhalgh, Mark D., Brueckner, Alexander C., Walden, Daniel M., Elías-Rodríguez, Pilar, Roberts, Patrick, Young, Benjamin G., West, Thomas H., Slawin, Alexandra M. Z., Ha-Yeon Cheong, Paul and Smith, Andrew D. (2019) Catalytic enantioselective synthesis of perfluoroalkyl-substituted β-lactones via a concerted asynchronous [2 + 2] cycloaddition : a synthetic and computational study. Chemical Science, 10 (24). pp. 6162-6173. doi:10.1039/C9SC00390H ISSN 2041-6520.

Neate, Peter G. N., Greenhalgh, Mark D., Brennessel, William W., Thomas, Stephen P. and Neidig, Michael L. (2019) Mechanism of the bis(imino)pyridine-iron-catalyzed hydromagnesiation of styrene derivatives. Journal of the American Chemical Society, 141 (25). pp. 10099-10108. doi:10.1021/jacs.9b04869 ISSN 1520-5126.

2018

Greenhalgh, Mark D., Smith, Samuel M, Walden, Daniel M., Taylor, James E., Brice, Zamira, Robinson, Emily R. T., Fallan, Charlene, Cordes, David B., Slawin, Alexandra M. Z., Richardson, H. Camille, Grove, Markas A., Cheong, Paul Ha-Yeon and Smith, Andrew D. (2018) A C=O⋅⋅⋅Isothiouronium interaction dictates enantiodiscrimination in acylative kinetic resolutions of tertiary heterocyclic alcohols. Angewandte Chemie-International Edition, 57 (12). pp. 3200-3206. doi:10.1002/anie.201712456 ISSN 1433-7851.

2017

Matviitsuk, Anastassia, Greenhalgh, Mark D., Antúnez, Diego-Javier Barrios, Slawin, Alexandra M. Z. and Smith, Andrew D. (2017) Aryloxide-facilitated catalyst turnover in enantioselective α,β-unsaturated acyl ammonium catalysis. Angewandte Chemie International Edition, 56 (40). pp. 12282-12287. doi:10.1002/anie.201706402 ISSN 1433-7851.