2023

Krämer, Tobias, Gyton, Matthew R., Bustos, I., Sinclair, M. J. G., Tan, Sze-yin, Wedge, C. J., Macgregor, S. A. and Chaplin, Adrian B. (2023) Stability and C–H bond activation reactions of palladium(I) and platinum(I) metalloradicals : carbon-to-metal H-atom transfer and an organometallic radical rebound mechanism. Journal of the American Chemical Society, 145 (25). pp. 14087-14100. doi:10.1021/jacs.3c04167 ISSN 0002-7863.

Emerson-King, Jack, Pan, Sudip, Gyton, Matthew R., Tonner-Zech, Ralf and Chaplin, Adrian B. (2023) Synthesis of a rhodium(III) dinitrogen complex using a calix[4]arene-based diphosphine ligand. Chemical Communications, 59 (15). pp. 2150-2152. doi:10.1039/D2CC06837K ISSN 1359-7345.

2020

Leforestier, Baptiste, Gyton, Matthew R. and Chaplin, Adrian B. (2020) Oxidative addition of a mechanically entrapped C(sp)–C(sp) bond to a rhodium(I) pincer complex. Angewandte Chemie International Edition, 59 (52). pp. 23500-23504. doi:10.1002/anie.202009546 ISSN 1433-7851.

Storey, Caroline M., Gyton, Matthew R., Andrew, Rhiann E. and Chaplin, Adrian B. (2020) Terminal alkyne coupling reactions through a ring : effect of ring size on rate and regioselectivity. Chemistry - A European Journal, 26 (64). pp. 14715-14723. doi:10.1002/chem.202002962 ISSN 0947-6539.

Gyton, Matthew R., Kynman, Amy E., Leforestier, Baptiste, Gallo, Angello, Lewandowski, Józef R. and Chaplin, Adrian B. (2020) Isolation and structural characterisation of rhodium(III) η2–fluoroarene complexes : experimental verification of predicted regioselectivity. Dalton Transactions, 49 . pp. 5791-5793. doi:10.1039/D0DT01137A ISSN 1477-9226.

Leforestier, Baptiste, Gyton, Matthew R. and Chaplin, Adrian B. (2020) Synthesis and group 9 complexes of macrocyclic PCP and POCOP pincer ligands. Dalton Transactions, 49 (7). pp. 2087-2101. doi:10.1039/C9DT04835A ISSN 1477-9226.

Storey, Caroline M., Kalpokas, Audrius, Gyton, Matthew R., Krämer, Tobias and Chaplin, Adrian B. (2020) A shape changing tandem Rh(CNC) catalyst : preparation of bicyclo[4.2.0]octa-1,5,7-trienes from terminal aryl alkynes. Chemical Science, 11 (8). pp. 2051-2057. doi:10.1039/C9SC06153C ISSN 2041-6520.

Hood, Thomas M., Gyton, Matthew R. and Chaplin, Adrian B. (2020) Synthesis and rhodium complexes of macrocyclic PNP and PONOP pincer ligands. Dalton Transactions, 49 (7). pp. 2077-2086. doi:10.1039/C9DT04474D ISSN 1477-9226.

2019

Gyton, Matthew R., Leforestier, Baptiste and Chaplin, Adrian B. (2019) Rhodium(I) pincer complexes of nitrous oxide. Angewandte Chemie International Edition, 58 (43). pp. 15295-15298. doi:10.1002/anie.201908333 ISSN 1433-7851.

Gyton, Matthew R., Bhadbhade, Mohan and Cole, Marcus L. (2019) A flexible, extremely sterically demanding triazenide ligand : synthesis and coordination chemistry. Zeitschrift fur anorganische und allgemeine Chemie, 645 (11). pp. 768-776. doi:10.1002/zaac.201900050 ISSN 00442313.

Hood, Thomas M., Leforestier, Baptiste, Gyton, Matthew R. and Chaplin, Adrian B. (2019) Synthesis and structural dynamics of five-coordinate Rh(III) and Ir(III) PNP and PONOP pincer complexes. Inorganic Chemistry, 58 (11). pp. 7593-7601. doi:10.1021/acs.inorgchem.9b00957 ISSN 0020-1669.

Gyton, Matthew R., Hood, Thomas M. and Chaplin, Adrian B. (2019) A convenient method for the generation of {Rh(PNP)}+ and {Rh(PONOP)}+ fragments : reversible formation of vinylidene derivatives. Dalton Transactions, 9 . 2877. ISSN 1477-9226.

2018

Gyton, Matthew R., Leforestier, Baptiste and Chaplin, Adrian B. (2018) Rhodium(III) and iridium(III) complexes of a NHC-based macrocycle : persistent weak agostic interactions and reactions with dihydrogen. Organometallics, 37 (21). pp. 3963-3971. doi:10.1021/acs.organomet.8b00595 ISSN 0276-7333.

Storey, Caroline M., Gyton, Matthew R., Andrew, Rhiann E. and Chaplin, Adrian B. (2018) Terminal alkyne coupling reactions through a ring : mechanistic insights and regiochemical switching. Angewandte Chemie International Edition, 57 (37). pp. 12003-12006. doi:10.1002/anie.201807028 ISSN 1433-7851.