2020

Georgiou, Panagiotis G., Baker, Alexander, Richards, Sarah-Jane, Laezza, Antonio, Walker, Marc and Gibson, Matthew I. (2020) “Tuning aggregative versus non-aggregative lectin binding with glycosylated nanoparticles by the nature of the polymer ligand”. Journal of Materials Chemistry B . doi:10.1039/C9TB02004G (In Press)

Georgiou, Panagiotis G., Kontopoulou, Ioanna, Congdon, Thomas R. and Gibson, Matthew I. (2020) Data for Ice recrystallisation inhibiting polymer nano-objects via saline-tolerant polymerisation-induced self-assembly. [Dataset]

Stubbs, Christopher D., Murray, Kathryn, Ishibe, Toru, Mathers, Robert T. and Gibson, Matthew I. (2020) Data for Combinatorial biomaterials discovery strategy to identify new macromolecular cryoprotectants. [Dataset]

Fayter, Alice E. R., Huband, Steven and Gibson, Matthew I. (2020) Data for X-ray diffraction to probe the kinetics of ice recrystallization inhibition. [Dataset]

Fayter, Alice E. R., Huband, Steven and Gibson, Matthew I. (2020) X-ray diffraction to probe the kinetics of ice recrystallization inhibition. The Analyst . doi:10.1039/C9AN02141H (In Press)

Richards, Sarah-Jane, Baker, Alexander, Walker, Marc and Gibson, Matthew I. (2020) Polymer-stabilized sialylated nanoparticles : synthesis, optimization, and differential binding to influenza hemagglutinins. Biomacromolecules, 21 (4). pp. 1604-1612. doi:10.1021/acs.biomac.0c00179

Gibson, Matthew I., Georgiou, Panagiotis G., Baker, Alexander, Richards, Sarah-Jane, Walker, Marc and Laezza, Antonio (2020) Data for Tuning aggregative versus non-aggregative lectin binding with glycosylated nanoparticles by the nature of the polymer ligand. [Dataset]

Tomás, Ruben M. F., Bailey, Trisha L., Hasan, Muhammad and Gibson, Matthew I. (2020) Data for Extracellular antifreeze protein significantly enhances the cryopreservation of cell monolayers. [Dataset]

Stubbs, Christopher D., Murray, Kathryn, Ishibe, Toru, Mathers, Robert T. and Gibson, Matthew I. (2020) Combinatorial biomaterials discovery strategy to identify new macromolecular cryoprotectants. ACS Macro Letters, 9 (2). pp. 290-294. doi:10.1021/acsmacrolett.0c00044

Wright, Robyn J., Bosch, Rafael, Gibson, Matthew I. and Christie-Oleza, Joseph Alexander (2020) R : Plasticizer degradation by marine bacterial isolates : a proteogenomic and metabolomic characterization. Environmental Science & Technology . doi:10.1021/acs.est.9b05228 (In Press)

Georgiou, Panagiotis G., Kontopoulou, Ioanna, Congdon, Thomas R. and Gibson, Matthew I. (2020) Ice recrystallisation inhibiting polymer nano-objects via saline-tolerant polymerisation-induced self-assembly. Materials Horizons . doi:10.1039/D0MH00354A (In Press)

2019

Graham, Ben, Fayter, Alice E. R. and Gibson, Matthew I. (2019) Synthesis of anthracene conjugates of truncated antifreeze protein sequences : effect of the end group and photocontrolled dimerization on ice recrystallization inhibition activity. Biomacromolecules, 20 (12). pp. 4611-4621. doi:10.1021/acs.biomac.9b01538

Stubbs, Christopher D., Congdon, Thomas R., Davis, Jessica, Lester, Daniel, Richards, Sarah-Jane and Gibson, Matthew I. (2019) High-throughput tertiary amine deoxygenated photopolymerizations for synthesizing polymer libraries. Macromolecules, 52 (20). pp. 7603-7612. doi:10.1021/acs.macromol.9b01714

Stubbs, Christopher D., Congdon, Thomas R., Davis, Jessica, Lester, Daniel, Richards, Sarah-Jane and Gibson, Matthew I. (2019) Data for High-throughput tertiary amine deoxygenated photopolymerizations for synthesizing polymer libraries. [Dataset]

Tomás, Ruben M. F., Bailey, Trisha L., Hasan, Muhammad and Gibson, Matthew I. (2019) Extracellular antifreeze protein significantly enhances the cryopreservation of cell monolayers. Biomacromolecules, 20 (10). pp. 3864-3872. doi:10.1021/acs.biomac.9b00951

Stubbs, Christopher D., Bailey, Trisha L., Murray, Kathryn and Gibson, Matthew I. (2019) Polyampholytes as emerging macromolecular cryoprotectants. Biomacromolecules . doi:10.1021/acs.biomac.9b01053 (In Press)

Ishibe, Toru, Congdon, Thomas R., Stubbs, Christopher D., Hasan, Muhammad, Sosso, Gabriele C. and Gibson, Matthew I. (2019) Enhancement of macromolecular ice recrystallization inhibition activity by exploiting depletion forces. ACS Macro Letters, 8 (8). pp. 1063-1067. doi:10.1021/acsmacrolett.9b00386

Ishibe, Toru, Congdon, Thomas R., Stubbs, Christopher D., Hasan, Muhammad, Sosso, Gabriele C. and Gibson, Matthew I. (2019) Data for Enhancement of macromolecular ice recrystallization inhibition activity by exploiting depletion forces. [Dataset]

Bailey, Trisha L., Stubbs, Christopher, Murray, Kathryn, Tomás, Ruben M. F., Otten, Lucienne and Gibson, Matthew I. (2019) Data for Synthetically scalable poly(ampholyte) which dramatically enhances cellular cryopreservation. [Dataset]

Guy, Collette S., Gibson, Matthew I. and Fullam, Elizabeth (2019) Targeting extracellular glycans : tuning multimeric boronic acids for pathogen-selective killing of Mycobacterium tuberculosis. Chemical Science, 10 (23). 5935-5942 . doi:10.1039/C9SC00415G

Bailey, Trisha L., Stubbs, Christopher D., Murray, Kathryn, Tomás, Ruben M. F., Otten, Lucienne and Gibson, Matthew I. (2019) Synthetically scalable poly(ampholyte) which dramatically enhances cellular cryopreservation. Biomacromolecules . doi:10.1021/acs.biomac.9b00681 (In Press)

Wilkins, Laura E., Hasan, Muhammad, Fayter, Alice E. R., Biggs, Caroline I., Walker, Marc and Gibson, Matthew I. (2019) Data for Site-specific conjugation of antifreeze proteins onto polymer-stabilized nanoparticles. [Dataset]

Wright, Robyn J., Gibson, Matthew I. and Christie-Oleza, Joseph Alexander (2019) Understanding microbial community dynamics to improve optimal microbiome selection. Microbiome, 7 (1). 85. doi:10.1186/s40168-019-0702-x

Gibson, Matthew I. and Tomás, Ruben M. F. (2019) Data for Optimization and stability of cell–polymer hybrids obtained by “clicking” synthetic polymers to metabolically labeled cell surface glycans. [Dataset]

Tomás, Ruben M. F. and Gibson, Matthew I. (2019) Optimization and stability of cell–polymer hybrids obtained by “clicking” synthetic polymers to metabolically labeled cell surface glycans. Biomacromolecules, 20 (7). pp. 2726-2736. doi:10.1021/acs.biomac.9b00478

Biggs, Caroline I., Stubbs, Christopher D., Graham, Ben, Fayter, Alice E. R., Hasan, Muhammad and Gibson, Matthew I. (2019) Mimicking the ice recrystallization activity of biological antifreezes. When is a new polymer “active”? Macromolecular Bioscience . 1900082. doi:10.1002/mabi.201900082 (In Press)

Erni-Cassola, Gabriel, Zadjelovic, Vinko, Gibson, Matthew I. and Christie-Oleza, Joseph Alexander (2019) Distribution of plastic polymer types in the marine environment ; a meta-analysis. Journal of Hazardous Materials, 369 . pp. 691-698. doi:10.1016/j.jhazmat.2019.02.067

Mitchell, Daniel A., Fayter, Alice, Deller, Robert C., Hasan, Muhammad, Gutierrez-Marcos, José F. and Gibson, Matthew I. (2019) Data for Ice-recrystallization inhibiting polymers protect proteins against freeze-stress and enable glycerol-free cryostorage. [Dataset]

Mitchell, Daniel A., Fayter, Alice, Deller, Robert C., Hasan, Muhammad, Gutierrez-Marcos, José F. and Gibson, Matthew I. (2019) Ice-recrystallization inhibiting polymers protect proteins against freeze-stress and enable glycerol-free cryostorage. Materials Horizons, 6 (2). pp. 354-368. doi:10.1039/c8mh00727f (In Press)

Wilkins, Laura E., Hasan, Muhammad, Fayter, Alice E. R., Biggs, Caroline I., Walker, Marc and Gibson, Matthew I. (2019) Site-specific conjugation of antifreeze proteins onto polymer-stabilized nanoparticles. Polymer Chemistry . doi:10.1039/c8py01719k (In Press)

Stubbs, Christopher, Congdon, Thomas R. and Gibson, Matthew I. (2019) Data for Photo-polymerisation and study of the ice recrystallisation inhibition of hydrophobically modified poly(vinyl pyrrolidone) co-polymers. [Dataset]

Stubbs, Christopher, Congdon, Thomas R. and Gibson, Matthew I. (2019) Photo-polymerisation and study of the ice recrystallisation inhibition of hydrophobically modified poly(vinyl pyrrolidone) co-polymers. European Polymer Journal, 110 . pp. 330-336. doi:10.1016/j.eurpolymj.2018.11.047

Martyn, Benjamin T., Biggs, Caroline I. and Gibson, Matthew I. (2019) Comparison of systematically functionalized heterogeneous and homogenous glycopolymers as toxin inhibitors. Journal of Polymer Science Part A: Polymer Chemistry, 57 (1). pp. 40-47. doi:10.1002/pola.29279

Guy, Collette S., Murray, Kathryn, Gibson, Matthew I. and Fullam, Elizabeth (2019) Dimeric benzoboroxoles for targeted activity against Mycobacterium tuberculosis. Organic & Biomolecular Chemistry, 17 (43). pp. 9524-9528. doi:10.1039/C9OB02222H

2018

Wilkins, Laura E., Badi, Nezha, Du Pre, Filip and Gibson, Matthew I. (2018) Double-modified glycopolymers from thiolactones to modulate lectin selectivity and affinity. ACS Macro Letters, 7 . pp. 1498-1502. doi:10.1021/acsmacrolett.8b00825 (In Press)

Wilkins, Laura E., Badi, Nezha, Du Prez, Filip and Gibson, Matthew I. (2018) Double-Modified Glycopolymers from Thiolactones to Modulate Lectin Selectivity and Affinity. ACS Macro Letters, 7 (12). pp. 1498-1502. doi:10.1021/acsmacrolett.8b00825

Martyn, Benjamin T., Biggs, Caroline I. and Gibson, Matthew I. (2018) Comparison of systematically functionalized heterogeneous and homogenous glycopolymers as toxin inhibitors. Journal of Polymer Science Part A: Polymer Chemistry . doi:10.1002/pola.29279 (In Press)

Tomás, Ruben M. F., Martyn, Benjamin T., Bailey, Trisha L. and Gibson, Matthew I. (2018) Data for Engineering cell surfaces by covalent grafting of synthetic polymers to metabolically-labeled glycans. [Dataset]

Tomás, Ruben M. F., Martyn, Benjamin T., Bailey, Trisha L. and Gibson, Matthew I. (2018) Engineering cell surfaces by covalent grafting of synthetic polymers to metabolically-labeled glycans. ACS Macro Letters, 2018 (7). pp. 1289-1294. doi:10.1021/acsmacrolett.8b00675

Hasan, Muhammad, Fayter, Alice E. R. and Gibson, Matthew I. (2018) Data for Ice recrystallization inhibiting polymers enable glycerol-free cryopreservation of microorganisms. [Dataset]

Richards, Sarah-Jane, Jones, Adam, Tomás, Ruben M. F. and Gibson, Matthew I. (2018) Photochemical “in-air” combinatorial discovery of antimicrobial co-polymers. Chemistry - A European Journal, 24 (52). pp. 13758-13761. doi:10.1002/chem.201802594

Stubbs, Christopher D. (David), Wilkins, Laura E., Fayter, Alice, Walker, Marc and Gibson, Matthew I. (2018) Data for Multivalent presentation of ice recrystallization inhibiting polymers on nanoparticles retains activity. [Dataset]

Stubbs, Christopher D. , Wilkins, Laura E., Fayter, Alice, Walker, Marc and Gibson, Matthew I. (2018) Multivalent presentation of ice recrystallization inhibiting polymers on nanoparticles retains activity. Langmuir . doi:10.1021/acs.langmuir.8b01952 (In Press)

Fayter, Alice E. R., Gibson, Matthew I. and Draper, Emily R. (2018) Sub-zero temperature mechanically stable low molecular weight hydrogels. Journal of Materials Chemistry B . doi:10.1039/C8TB01668B (In Press)

Blackman, Lewis D., Varlas, Spyridon, Arno, Maria Chiara, Houston, Zachary H., Fletcher, Nicholas L., Thurecht, Kristofer J., Hasan, Muhammad, Gibson, Matthew I. and O’Reilly, Rachel K. (2018) Confinement of therapeutic enzymes in selectively permeable polymer vesicles by polymerization-induced self-assembly (PISA) reduces antibody binding and proteolytic susceptibility. ACS Central Science, 4 (6). pp. 718-723. doi:10.1021/acscentsci.8b00168

Hasan, Muhammad, Fayter, Alice E. R. and Gibson, Matthew I. (2018) Ice recrystallization inhibiting polymers enable glycerol-free cryopreservation of microorganisms. Biomacromolecules, 19 (8). pp. 3371-3376. doi:10.1021/acs.biomac.8b00660 (In Press)

Graham, Ben, Fayter, Alice, Houston, Judith E., Evans, Rachel C. and Gibson, Matthew I. (2018) Facially amphipathic glycopolymers inhibit ice recrystallization. Journal of the American Chemical Society, 140 (17). pp. 5682-5685. doi:10.1021/jacs.8b02066 (In Press)

Won, Sangho, Hindmarsh, Steven A. and Gibson, Matthew I. (2018) Triggerable multivalent glyconanoparticles for probing carbohydrate–carbohydrate interactions. ACS Macro Letters, 7 . pp. 178-183. doi:10.1021/acsmacrolett.7b00891

Martyn, Benjamin T., Won, Sangho, Richards, Sarah-Jane and Gibson, Matthew I. (2018) Glycan engineering at nanoparticle surfaces to understand and detect infection. In: 255th ACS National Meeting - Nexus of Food, Energy, and Water, New Orleans, LA, U.S.A., March 18-22, 2018. Published in: Abstracts of papers of the American Chemical Society, 255 ISSN 0065-7727.

Varlas, Spyridon, Blackman, Lewis D., Findlay, Heather E., Reading, Eamonn, Booth, Paula J., Gibson, Matthew I. and O’Reilly, Rachel K. (2018) Photoinitiated polymerization-induced self-assembly in the presence of surfactants enables membrane protein incorporation into vesicles. Macromolecules, 51 (16). pp. 6190-6201. doi:10.1021/acs.macromol.8b00994

2017

Graham, Ben, Bailey, Trisha L., Healey, Joseph R. J., Marcellini, Moreno, Deville, Sylvain and Gibson, Matthew I. (2017) Polyproline as a minimal antifreeze proteinmimic that enhances the cryopreservation of cell monolayers. Angewandte Chemie International Edition, 56 (50). pp. 15941-15944. doi:10.1002/anie.201706703

Graham, Ben, Bailey, Trisha L., Healey, Joseph R. J., Marcellini, Moreno, Deville, Sylvain and Gibson, Matthew I. (2017) Polyproline is a minimal antifreeze protein mimetic and enhances the cryopreservation of cell monolayers. Angewandte Chemie International Edition, 56 (50). pp. 15941-15944. doi:10.1002/anie.201706703

Erni-Cassola, Gabriel, Gibson, Matthew I., Thompson, Richard C. and Christie-Oleza, Joseph Alexander (2017) Lost, but found with Nile red ; a novel method to detect and quantify small microplastics (20 µm–1 mm) in environmental samples. Environmental Science & Technology, 51 (23). pp. 13641-13648. doi:10.1021/acs.est.7b04512

Richards, Sarah-Jane, Isulfi, Klea, Wilkins, Laura E., Lipecki, Julia, Fullam, Elizabeth and Gibson, Matthew I. (2017) Multivalent antimicrobial polymer nanoparticles target mycobacteria and gram-negative bacteria by distinct mechanisms. Biomacromolecules, 19 (1). pp. 256-264. doi:10.1021/acs.biomac.7b01561

Hedir, Guillaume, Stubbs, Christopher D., Aston, Phillip, Dove, Andrew P. and Gibson, Matthew I. (2017) Synthesis of degradable poly(vinyl alcohol) by radical ring-opening copolymerization and ice recrystallization inhibition activity. ACS Macro Letters, 6 (12). pp. 1404-1408.

Blackman, Lewis D., Varlas, Spyridon, Arno, Maria Chiara, Fayter, Alice, Gibson, Matthew I. and O’Reilly, Rachel K. (2017) Permeable protein-loaded polymersome cascade nanoreactors by polymerization-induced self-assembly. ACS Macro Letters, 6 (11). pp. 1263-1267. doi:10.1021/acsmacrolett.7b00725

Biggs, Caroline I., Bailey, Trisha L., Graham, Ben, Stubbs, Christopher D., Fayter, Alice and Gibson, Matthew I. (2017) Polymer mimics of biomacromolecular antifreezes. Nature Communications, 8 . 1546. doi:10.1038/s41467-017-01421-7

Casillo, Angela, Ståhle, Jonas, Parrilli, Ermenegilda, Sannino, Filomena, Mitchell, Daniel E., Pieretti, Giuseppina, Gibson, Matthew I., Marino, Gennaro, Lanzetta, Rosa, Parrilli, Michelangelo, Widmalm, Göran, Tutino, Maria L. and Corsaro, Maria M. (2017) Structural characterization of an all-aminosugar-containing capsular polysaccharide from Colwellia psychrerythraea 34H. Antonie van Leeuwenhoek, 110 (11). pp. 1377-1387. doi:10.1007/s10482-017-0834-6

Vial, N., Stubbs, Christopher D., Biggs, Caroline I. and Gibson, Matthew I. (2017) Ultralow dispersity poly(vinyl alcohol) reveals significant dispersity effects on ice recrystallization inhibition activity. ACS Macro Letters, 6 (9). pp. 1001-1004. doi:10.1021/acsmacrolett.7b00595

Biggs, Caroline I., Packer, Christopher, Hindmarsh, Steven A., Walker, Marc, Wilson, Neil R., Rourke, Jonathan and Gibson, Matthew I. (2017) Impact of sequential surface-modification of graphene oxide on ice nucleation. Physical Chemistry Chemical Physics, 19 . 21929-21932 . doi:10.1039/C7CP03219F

Vail, Laura, Stubbs, Christopher D., Biggs, Caroline I. and Gibson, Matthew I. (2017) Ultralow Dispersity Poly(vinyl alcohol) Reveals Significant Dispersity Effects on Ice Recrystallization Inhibition Activity. ACS Macro Letters, 6 (9). pp. 1001-1004. doi:10.1021/acsmacrolett.7b00595

Mitchell, Daniel E., Clarkson, Guy J., Fox, David J., Vipond, Rebecca A. (Ann), Scott, Peter and Gibson, Matthew I. (2017) Antifreeze protein mimetic metallohelices with potent ice recrystallization inhibition activity. Journal of the American Chemical Society, 139 (29). pp. 9835-9838. doi:10.1021/jacs.7b05822

Laezza, Antonio, Casillo, Angela, Cosconati, Sandro, Biggs, Caroline I., Fabozzi, Antonio, Paduano, Luigi, Iadonisi, Alfonso, Novellino, Ettore, Gibson, Matthew I., Randazzo, Antonio, Corsaro, Maria M. and Bedini, Emiliano (2017) Decoration of chondroitin polysaccharide with threonine : synthesis, conformational study, and ice-recrystallization inhibition activity. Biomacromolecules . doi:10.1021/acs.biomac.7b00326

Guy, Collette S., Tichauer, Esther, Kay, Gemma L., Phillips, Daniel J., Bailey, Trisha L., Harrison, James, Furze, Christopher M., Millard, Andrew D., Gibson, Matthew I., Pallen, Mark J. and Fullam, Elizabeth (2017) Identification of the anti-mycobacterial functional properties of piperidinol derivatives. British Journal of Pharmacology, 174 (14). pp. 2183-2193. doi:10.1111/bph.13744

Doncom, Kay E. B., Blackman, Lewis D., Wright, Daniel Bayham, Gibson, Matthew I. and O'Reilly, Rachel K. (2017) Dispersity effects in polymer self-assemblies : a matter of hierarchical control. Chemical Society Reviews, 46 . 4119-4134 . doi:10.1039/c6cs00818f

Blackman, Lewis D., Doncom, Kay E. B., Gibson, Matthew I. and O'Reilly, Rachel K. (2017) Comparison of photo- and thermally initiated polymerization-induced self-assembly : a lack of end group fidelity drives the formation of higher order morphologies. Polymer Chemistry, 8 (18). pp. 2860-2871. doi:10.1039/C7PY00407A

Phillips, Daniel J., Harrison, James, Richards, Sarah-Jane, Mitchell, Daniel E., Tichauer, Esther, Hubbard, Alasdair T. M., Guy, Collette S., Hands-Portman, Ian, Fullam, Elizabeth and Gibson, Matthew I. (2017) Evaluation of the antimicrobial activity of cationic polymers against mycobacteria : toward antitubercular macromolecules. Biomacromolecules, 18 (5). pp. 1592-1599. doi:10.1021/acs.biomac.7b00210

Ieong , Nga Sze, Biggs, Caroline I., Walker , Mark and Gibson, Matthew I. (2017) Comparison of RAFT derived poly(vinylpyrolidone) verses Poly(oligoethyleneglycol methacrylate) for the stabilization of glycosylated gold nanoparticles. Journal of Polymer Science Part A : Polymer Chemistry, 55 (7). pp. 1200-1280. doi:10.1002/pola.28481

Freese, C., Anspach, L., Deller, Robert C., Richards, Sarah-Jane, Gibson, Matthew I., Kirkpatrick, C. J. and Unger, R. E. (2017) Gold nanoparticle interactions with endothelial cells cultured under physiological conditions. Biomaterials Science, 5 (4). pp. 707-717. doi:10.1039/C6BM00853D

Won, Sangho, Richards, Sarah-Jane, Walker, Marc and Gibson, Matthew I. (2017) Externally controllable glycan presentation on nanoparticle surfaces to modulate lectin recognition. Nanoscale Horizons, 2017 (2). pp. 106-109. doi:10.1039/C6NH00202A

Congdon, Thomas R., Notman, Rebecca and Gibson, Matthew I. (2017) Synthesis of star-branched poly(vinyl alcohol) and ice recrystallization inhibition activity. European Polymer Journal, 88 . pp. 320-327. doi:10.1016/j.eurpolymj.2017.01.039

Casillo, Angela, Parrilli, Ermenegilda, Sannino, Filomena, Mitchell, Daniel E., Gibson, Matthew I., Marino, Gennaro, Lanzetta, Rosa, Parilli, Michelangelo, Cosconati, Sandro, Novellino, Ettore, Randazzo, Antonio, Tutino, Maria and Corsaro, Michela (2017) Structure-activity relationship of the exopolysaccharide from a psychrophilic bacterium : a strategy for cryoprotection. Carbohydrate Polymers, 156 . pp. 364-371. doi:10.1016/j.carbpol.2016.09.037

Stubbs, Christopher D., Lipecki, Julia and Gibson, Matthew I. (2017) Regioregular alternating polyampholytes have enhanced biomimetic ice recrystallization activity compared to random copolymers and the role of side chain verses main chain hydrophobicity. Biomacromolecules, 18 (1). pp. 295-302. doi:10.1021/acs.biomac.6b01691

2016

Gibson, Matthew I. (2016) Coating the flu with sticky polymers to look for new drugs. ACS Central Science, 2 (10). pp. 682-684. doi:10.1021/acscentsci.6b00301

Won, Sangho, Phillips, Daniel J., Walker, Marc and Gibson, Matthew I. (2016) Co-operative transitions of responsive-polymer coated gold nanoparticles ; precision tuning and direct evidence for co-operative aggregation. Journal of Materials Chemistry B, 4 (34). pp. 5673-5682. doi:10.1039/c6tb01336h

Otten, Lucienne, Vlachou, Denise, Richards, Sarah-Jane and Gibson, Matthew I. (2016) Glycan heterogeneity on gold nanoparticles increases lectin discrimination capacity in label-free multiplexed bioassays. Analyst, 141 (14). pp. 4305-4312. doi:10.1039/c6an00549g

Biggs, Caroline I., Walker, Marc and Gibson, Matthew I. (2016) ‘Grafting to’ of RAFTed responsive polymers to glass substrates by thiol-ene and critical comparison to thiol-gold coupling. Biomacromolecules, 17 (8). pp. 2626-2633. doi:10.1021/acs.biomac.6b00662

Deller, Robert C., Pessin, Jeffrey E., Vatish, Manu, Mitchell, Daniel A. and Gibson, Matthew I. (2016) Enhanced non-vitreous cryopreservation of immortalized and primary cells by ice-growth inhibiting polymers. Biomaterials Science, 4 (7). pp. 1079-1084. doi:10.1039/c6bm00129g

Mitchell, Daniel E., Lovett, Joseph R., Armes, Steven P. and Gibson, Matthew I. (2016) Combining biomimetic block copolymer worms with an ice-inhibiting polymer for the solvent-free cryopreservation of red blood cells. Angewandte Chemie International Edition, 128 (8). pp. 2851-2854. doi:10.1002/anie.201511454

Otten, Lucienne, Fullam, Elizabeth and Gibson, Matthew I. (2016) Discrimination between bacterial species by ratiometric analysis of their carbohydrate binding profile. Molecular BioSystems, 12 (2). pp. 341-344. doi:10.1039/c5mb00720h

Phillips, Daniel J., Congdon, Thomas R. and Gibson, Matthew I. (2016) Activation of ice recrystallization inhibition activity of poly(vinyl alcohol) using a supramolecular trigger. Polymer Chemistry, 7 . pp. 1701-1704. doi:10.1039/c5py01948f

Blackman, Lewis D., Gibson, Matthew I. and O'Reilly, Rachel K. (2016) Probing the causes of thermal hysteresis using tunable Nagg micelles with linear and brush-like thermoresponsive coronas. Polymer Chemistry, 8 . pp. 233-243. doi:10.1039/C6PY01191H

Anspach, Laura, Unger, Ronald E., Brochhausen, Christoph, Gibson, Matthew I., Klok, Harm-Anton, Kirkpatrick, C. James and Freese, Christian (2016) Impact of polymer-modified gold nanoparticles on brain endothelial cells : exclusion of endoplasmic reticulum stress as a potential risk factor. Nanotoxicology, 10 (9). pp. 1341-1350. doi:10.1080/17435390.2016.1214761

2015

Thomas, Helen R., Phillips, Daniel J., Wilson, Neil R., Gibson, Matthew I. and Rourke, Jonathan (2015) One-step grafting of polymers to graphene oxide. Polymer Chemistry, 6 (48). pp. 8270-8274. doi:10.1039/c5py01358e

Richards, Sarah-Jane, Otten, Lucienne and Gibson, Matthew I. (2015) Glycosylated gold nanoparticle libraries for label-free multiplexed lectin biosensing. Journal of Materials Chemistry B . doi:10.1039/c5tb01994j

Mitchell, Daniel E., Congdon, Thomas R., Rodger, Alison and Gibson, Matthew I. (2015) Gold nanoparticle aggregation as a probe of antifreeze (glyco) protein-inspired ice recrystallization inhibition and identification of new IRI active macromolecules. Scientific Reports, 5 . 15716. doi:10.1038/srep15716

Blackman, Lewis D., Wright, Daniel Bayham, Robin, Mathew P., Gibson, Matthew I. and O’Reilly, Rachel K. (2015) Effect of micellization on the thermoresponsive behavior of polymeric assemblies. ACS Macro Letters, 4 (11). pp. 1210-1214. doi:10.1021/acsmacrolett.5b00551

Mitchell, Daniel E. and Gibson, Matthew I. (2015) Latent ice recrystallization inhibition activity in nonantifreeze proteins : Ca2+-activated plant lectins and cation-activated antimicrobial peptides. Biomacromolecules, 16 (10). pp. 3411-3416. doi:10.1021/acs.biomac.5b01118

Deller, Robert C., Vatish, Manu, Mitchell, Daniel E. and Gibson, Matthew I. (2015) Glycerol free cryopreservation of red blood cells enabled by ice recrystallization inhibiting polymers. Biomaterials Science and Engineering, 1 (9). pp. 789-794. doi:10.1021/acsbiomaterials.5b00162

Congdon, Thomas R., Dean, Bethany T., Kasperczak-Wright, James, Biggs, Caroline I., Notman, Rebecca and Gibson, Matthew I. (2015) Probing the biomimetic ice nucleation inhibition activity of poly(vinyl alcohol) and comparison to synthetic and biological polymers. Biomacromolecules, 16 (9). pp. 2820-2826. 150810155641002. doi:10.1021/acs.biomac.5b00774

Phillips, Daniel J., Wilde, Marleen, Greco, Francesca and Gibson, Matthew I. (2015) Enzymatically-triggered, isothermally responsive polymers : re-programming poly(oligoethylene glycols) to respond to phosphatase. Biomacromolecules, 16 (10). pp. 3256-3264. doi:10.1021/acs.biomac.5b00929

Mitchell, Daniel E., Cameron, Neil R. and Gibson, Matthew I. (2015) Rational, yet simple, design and synthesis of an antifreeze-protein inspired polymer for cellular cryopreservation. Chemical Communications, 51 (65). pp. 12977-12980. doi:10.1039/c5cc04647e

Congdon, Thomas R., Shaw, Peter and Gibson, Matthew I. (2015) Thermoresponsive, well-defined, poly(vinyl alcohol) co-polymers. Polymer chemistry, 6 (26). pp. 4749-4757. doi:10.1039/c5py00775e

Otten, Lucienne and Gibson, Matthew I. (2015) Discrimination between lectins with similar specificities by ratiometric profiling of binding to glycosylated surfaces ; a chemical ‘tongue’ approach. RSC Advances , 5 (66). pp. 53911-53914. doi:10.1039/c5ra08857g

Raeburn, Jaclyn, Chen, Lin, Awhida, Salmah, Deller, Robert C., Vatish, Manu, Gibson, Matthew I. and Adams, Dave J. (2015) Using molecular rotors to probe gelation. Soft matter, 11 (18). pp. 3706-3713. doi:10.1039/c5sm00456j

Lowery, Richard, Gibson, Matthew I., Thompson, Richard C. and Fullam, Elizabeth (2015) Deuterated carbohydrate probes as ‘label-free’ substrates for probing nutrient uptake in mycobacteria by nuclear reaction analysis. Chemical communications, 51 (23). pp. 4838-4841. doi:10.1039/c4cc09588j

Phillips, Daniel J. and Gibson, Matthew I. (2015) Towards being genuinely smart : ‘isothermally-responsive’ polymers as versatile, programmable scaffolds for biologically-adaptable materials. Polymer chemistry, 6 (7). pp. 1033-1043. doi:10.1039/c4py01539h

Phillips, Daniel J., Davies, Gemma L. and Gibson, Matthew I. (2015) Siderophore-inspired nanoparticle-based biosensor for the selective detection of Fe3+. Journal of Materials Chemistry B, 3 (2). pp. 270-275. doi:10.1039/c4tb01501k

Biggs, Caroline I., Edmondson, Steve and Gibson, Matthew I. (2015) Thiol–ene immobilisation of carbohydrates onto glass slides as a simple alternative to gold–thiol monolayers, amines or lipid binding. Biomaterials Science, 3 (1). pp. 175-181. doi:10.1039/c4bm00176a

Congdon, Thomas R., Wilmet, Charline, Williams, Rebecca J., Polt, Julia, Lilliman, Mary and Gibson, Matthew I. (2015) Diversely functionalised carbohydrate-centered oligomers and polymers. Thermoresponsivity, lectin binding and degradability. European Polymer Journal, 62 . pp. 352-362. doi:10.1016/j.eurpolymj.2014.06.001

2014

Phillips, Daniel J., Prokes, Ivan, Davies, Gemma L. and Gibson, Matthew I. (2014) Isothermally-responsive polymers triggered by selective binding of Fe3+to siderophoric catechol end-groups. ACS Macro Letters, 3 (12). pp. 1225-1229. doi:10.1021/mz500686w

Richards, Sarah-Jane and Gibson, Matthew I. (2014) Optimization of the polymer coating for glycosylated gold nanoparticle biosensors to ensure stability and rapid optical readouts. ACS Macro Letters, 3 (10). pp. 1004-1008. doi:10.1021/mz5004882

Mitchell, Daniel E., Lilliman, Mary, Spain, Sebastian G. and Gibson, Matthew I. (2014) Quantitative study on the antifreeze protein mimetic ice growth inhibition properties of poly(ampholytes) derived from vinyl-based polymers. Biomaterials Science, 2 (12). pp. 1787-1795. doi:10.1039/c4bm00153b

Phillips, Daniel J. and Gibson, Matthew I. (2014) Redox-sensitive materials for drug delivery : targeting the correct intracellular environment, tuning release rates, and appropriate predictive systems. Antioxidants & Redox Signaling, Volume 21 (Number 5). pp. 786-803. doi:10.1089/ars.2013.5728

Gibson, Matthew I., Neres, João and Fullam, Elizabeth (2014) Selective detection of epimeric pentose saccharides at physiological pH using a fluorescent receptor. Carbohydrate research, Volume 391 . pp. 61-65. doi:10.1016/j.carres.2014.02.007

Lu, Jiawei, Zhang, Weidong, Richards, Sarah-Jane, Gibson, Matthew I. and Chen, Gaojian (2014) Glycopolymer-coated gold nanorods synthesised by a one pot copper(0) catalyzed tandem RAFT/click reaction. Polymer Chemistry, Volume 5 (Number 7). pp. 2326-2332. doi:10.1039/c3py01526b

Jones, Mathew W., Otten, Lucienne, Richards, Sarah-Jane, Lowery, Richard, Phillips, Daniel J., Haddleton, David M. and Gibson, Matthew I. (2014) Glycopolymers with secondary binding motifs mimic glycan branching and display bacterial lectin selectivity in addition to affinity. Chemical Science, 5 (4). pp. 1611-1616. doi:10.1039/c3sc52982g

Richards, Sarah-Jane, Fullam, Elizabeth, Besra, Gurdyal S. and Gibson, Matthew I. (2014) Discrimination between bacterial phenotypes using glyco-nanoparticles and the impact of polymer coating on detection readouts. Journal of Materials Chemistry B, Volume 2 (Number 11). pp. 1490-1498. doi:10.1039/c3tb21821j

Wilkinson, Laura, Phillips, Daniel J., Deller, Robert C., Davies, Gemma L. and Gibson, Matthew I. (2014) Synthesis and characterisation of glucose-functional glycopolymers and gold nanoparticles : study of their potential interactions with ovine red blood cells. Carbohydrate research, 405 . pp. 47-54. doi:10.1016/j.carres.2014.09.009

Deller, Robert C., Vatish, Manu, Mitchell, Daniel A. and Gibson, Matthew I. (2014) Synthetic polymers enable non-vitreous cellular cryopreservation by reducing ice crystal growth during thawing. Nature Communications, Volume 5 . Article number 3244. doi:10.1038/ncomms4244

Razmkhah, Kasra, Chmel, Nikola Paul, Gibson, Matthew I. and Rodger, Alison (2014) Oxidized polyethylene films for orienting polar molecules for linear dichroism spectroscopy. The analyst, 139 (6). pp. 1372-1382. doi:10.1039/c3an02322b

Phillips, Daniel J., Patterson, Joseph P., O'Reilly, Rachel K. and Gibson, Matthew I. (2014) Glutathione-triggered disassembly of isothermally responsive polymer nanoparticles obtained by nanoprecipitation of hydrophilic polymers. Polymer Chemistry, Volume 5 (Number 1). pp. 126-131. doi:10.1039/c3py00991b

2013

Gibson, Matthew I. and O'Reilly, Rachel K. (2013) To aggregate, or not to aggregate? considerations in the design and application of polymeric thermally-responsive nanoparticles. Chemical Society Reviews, Volume 42 (Number 17). pp. 7204-7213. doi:10.1039/c3cs60035a

Freese, Christian, Unger, Ronald E., Deller, Robert C., Gibson, Matthew I., Brochhausen, Christoph, Klok, Harm-Anton and Kirkpatrick, C. James (2013) Uptake of poly(2-hydroxypropylmethacrylamide)-coated gold nanoparticles in microvascular endothelial cells and transport across the blood–brain barrier. Biomaterials Science, Volume 1 (Number 8). pp. 824-833. doi:10.1039/c3bm60050e

Liu, Mi, Tirino, Pasquale, Radivojevic, Milos, Phillips, Daniel J., Gibson, Matthew I., Leroux, Jean-Christophe and Gauthier, Marc A. (2013) Molecular sieving on the surface of a protein provides protection without loss of activity. Advanced Functional Materials, Volume 23 (Number 16). pp. 2007-2015. doi:10.1002/adfm.201202227

Jones, Mathew W., Richards, Sarah-Jane, Haddleton, David M. and Gibson, Matthew I. (2013) Poly(azlactone)s : versatile scaffolds for tandem post-polymerisation modification and glycopolymer synthesis. Polymer Chemistry, Volume 4 (Number 3). pp. 717-723. doi:10.1039/c2py20757e

Congdon, Thomas R., Notman, Rebecca and Gibson, Matthew I. (2013) Antifreeze (Glyco)protein mimetic behavior of poly(vinyl alcohol) : detailed structure ice recrystallization inhibition activity study. Biomacromolecules, Volume 14 (Number 5). pp. 1578-1586. doi:10.1021/bm400217j

Otten, Lucienne, Richards, Sarah-Jane, Fullam, Elizabeth, Besra, Gurdyal S. and Gibson, Matthew I. (2013) Gold nanoparticle-linked analysis of carbohydrate–protein interactions, and polymeric inhibitors, using unlabelled proteins; easy measurements using a ‘simple’ digital camera. Journal of Materials Chemistry B, Volume 1 (Number 20). pp. 2665-2672. doi:10.1039/c3tb20259c

Deller, Robert C., Congdon, Thomas R., Sahid, Mohammed A., Morgan, Michael, Vatish, Manu, Mitchell, Daniel A., Notman, Rebecca and Gibson, Matthew I. (2013) Ice recrystallisation inhibition by polyols : comparison of molecular and macromolecular inhibitors and role of hydrophobic units. Biomaterials Science, Volume 1 (Number 5). pp. 478-485. doi:10.1039/c3bm00194f

Summers, Matthew J., Phillips, Daniel J. and Gibson, Matthew I. (2013) “Isothermal” LCST transitions triggered by bioreduction of single polymer end-groups. Chemical Communications, 49 (39). pp. 4223-4225. doi:10.1039/c2cc34236g

2012

Pache, Christophe, Bocchio, Noelia L., Bouwens, Arno, Villiger, Martin, Berclaz, Corinne, Goulley, Joan, Gibson, Matthew I., Santschi, Christian and Lasser, Theo (2012) Fast three-dimensional imaging of gold nanoparticles in living cells with photothermal optical lock-in Optical Coherence Microscopy. Optics Express, Volume 20 (Number 19). 21385-21399 . doi:10.1364/OE.20.021385

Saaka, Yussif, Deller, Robert C., Rodger, Alison and Gibson, Matthew I. (2012) Exploiting thermoresponsive polymers to modulate lipophilicity : interactions with model membranes. Macromolecular Rapid Communications, Vol.33 (No.9). pp. 779-784. doi:10.1002/marc.201100873

Gou, Yanzi, Richards, Sarah-Jane, Haddleton, David M. and Gibson, Matthew I. (2012) Investigation of glycopolymer–lectin interactions using QCM-d : comparison of surface binding with inhibitory activity. Polymer Chemistry, Volume 3 (Number 6). pp. 1634-1640. doi:10.1039/c2py20140b

Ieong, Nga Sze, Hasan, Muhammad, Phillips, Daniel J., Saaka, Yussif, O'Reilly, Rachel K. and Gibson, Matthew I. (2012) Polymers with molecular weight dependent LCSTs are essential for cooperative behaviour. Polymer Chemistry, Vol.3 (No.3). pp. 794-799. doi:10.1039/c2py00604a

Jones, Mathew W., Strickland, Rachel A., Schumacher, Feliz F., Caddick, Stephen, Baker, James R., Gibson, Matthew I. and Haddleton, David M. (2012) Polymeric dibromomaleimides as extremely efficient disulfide bridging bioconjugation and pegylation agents. Journal of the American Chemical Society, 134 (3). pp. 1847-1852. doi:10.1021/ja210335f

Phillips, Daniel J. and Gibson, Matthew I. (2012) Biodegradable Poly(disulfide)s Derived from RAFT Polymerization: Monomer Scope, Glutathione Degradation, and Tunable Thermal Responses. Biomacromolecules, Vol. 13 (No. 10). pp. 3200-3208. doi:10.1021/bm300989s

Phillips, Daniel J. and Gibson, Matthew I. (2012) Degradable thermoresponsive polymers which display redox-responsive LCST Behaviour. Chemical Communications, Vol.48 (No.7). 1054-1056 . doi:10.1039/c1cc16323j

Jones, Mathew W., Strickland, Rachel A., Schumacher, Felix F., Caddick, Stephen, Baker, James. R., Gibson, Matthew I. and Haddleton, David M. (2012) Highly efficient disulfide bridging polymers for bioconjugates from radical-compatible dithiophenol maleimides. Chemical Communications, Vol.48 (No.34). pp. 4064-4066. doi:10.1039/c2cc30259d

Richards, Sarah-Jane, Jones, Mathew W., Hunaban, Mark, Haddleton, David M. and Gibson, Matthew I. (2012) Probing bacterial-toxin inhibition with synthetic glycopolymers prepared by tandem post-polymerization modification : role of linker length and carbohydrate density. Angewandte Chemie International Edition, Vol.51 (No.31). pp. 7812-7816. doi:10.1002/anie.201202945

Freese, Christian, Gibson, Matthew I., Klok, Harm-Anton, Unger, Ronald E. and Kirkpatrick, C. James (2012) Size- and coating-dependent uptake of polymer-coated gold nanoparticles in primary human dermal microvascular endothelial cells. Biomacromolecules, Vol.13 (No.5). pp. 1533-1543. doi:10.1021/bm300248u

Freese, Christian, Uboldi, Chiara, Gibson, Matthew I., Unger, Ronald E., Weksler, Babette B., Romero, Ignacio A., Couraud, Pierre-Olivier and Kirkpatrick, C. J. (C. James) (2012) Uptake and cytotoxicity of citrate-coated gold nanospheres : comparative studies on human endothelial and epithelial cells. Particle and Fibre Toxicology, Vol.9 (No.1). p. 23. doi:10.1186/1743-8977-9-23

2011

Slavin, Stacy, Voorhaar, Lenny, Mitchell, Daniel A., Ilyas, Rebecca, Gibson, Matthew I., Haddleton, David M. and Becer, C. Remzi (2011) Synthesis of well-defined glycopolymers in various architectures and their interactions with DC-SIGN. In: 242nd National Meeting of the American-Chemical-Society (ACS), Denver, CO, 28 Aug - 1 Sep 2011. Published in: American Chemical Society. Abstracts of Papers (at the National Meeting), Vol.242 545-POLY. ISSN 0065-7727.

Singha, Nikhil K., Gibson, Matthew I., Koiry, Bishnu P., Danial, Maarten and Klok, Harm-Anton (2011) Side-chain peptide-synthetic polymer conjugates via tandem “ester-amide/thiol–ene” post-polymerization modification of poly(pentafluorophenyl methacrylate) obtained using ATRP. Biomacromolecules, Vol.12 (No.8). pp. 2908-2913. doi:10.1021/bm200469a

Gibson, Matthew I., Danial, Maarten and Klok, Harm-Anton (2011) Sequentially modified, polymer-stabilized gold nanoparticle libraries : convergent synthesis and aggregation behavior. ACS Combinatorial Science, Vol.13 (No.3). pp. 286-297. doi:10.1021/co100099r

Bebis, Konstantinos, Jones, Mathew W., Haddleton, David M. and Gibson, Matthew I. (2011) Thermoresponsive behaviour of poly[(oligo(ethyleneglycol methacrylate)]s and their protein conjugates : importance of concentration and solvent system. Polymer Chemistry, Vol.2 (No.4). pp. 975-982. doi:10.1039/c0py00408a

Jones, Mathew W., Gibson, Matthew I., Mantovani, Giuseppe and Haddleton, David M. (2011) Tunable thermo-responsive polymer–protein conjugates via a combination of nucleophilic thiol–ene “click” and SET-LRP. Polymer Chemistry, Vol.2 (No.3). pp. 572-574. doi:10.1039/c0py00329h

Vinson, Nicola, Gou, Yanzi, Becer, C. Remzi, Haddleton, David M. and Gibson, Matthew I. (2011) Optimised ‘click’ synthesis of glycopolymers with mono/di- and trisaccharides. Polymer Chemistry, Vol.2 (No.1). pp. 107-113. doi:10.1039/c0py00260g

Ieong, Nga Sze, Brebis, Konstantinos, Daniel, Laura E., O'Reilly, Rachel K. and Gibson, Matthew I. (2011) The critical importance of size on thermoresponsive nanoparticle transition temperatures : gold and micelle-based polymer nanoparticles. Chemical Communications, Vol.47 (No.42). pp. 11627-11629. doi:10.1039/c1cc15171a

2010

Gibson, Matthew I., Paripovic, Dusko and Klok, Harm-Anton (2010) Size-dependent LCST transitions of polymer-coated gold nanoparticles : cooperative aggregation and surface assembly. Advanced Materials, Vol.22 (No.42). pp. 4721-4725. doi:10.1002/adma.201001382

Becer, C. Remzi, Gibson, Matthew I., Geng, Jin, Ilyas, Rebecca, Wallis, Russell, Mitchell, Daniel A. and Haddleton, David M. (2010) High-affinity glycopolymer binding to human DC-SIGN and disruption of DC-SIGN interactions with HIV envelope glycoprotein. Journal of the American Chemical Society, Vol.132 (No.43). pp. 15130-15132. doi:10.1021/ja1056714

Gibson, Matthew I. (2010) Slowing the growth of ice with synthetic macromolecules : beyond antifreeze(glyco) proteins. Polymer Chemistry, Vol.1 (No.8). pp. 1141-1152. doi:10.1039/c0py00089b

2009

Gibson, Matthew I., Fröhlich, Eleonore and Klok, Harm-Anton (2009) Postpolymerization modification of poly(pentafluorophenyl methacrylate) : synthesis of a diverse water-soluble polymer library. Journal of Polymer Science Part A: Polymer Chemistry, Vol.47 (No.17). pp. 4332-4345. doi:10.1002/pola.23486

Gibson, Matthew I. and Cameron, Neil R. (2009) Experimentally facile controlled polymerization of N-carboxyanhydrides (NCAs), including O-benzyl-L-threonine NCA. Journal of Polymer Science Part A: Polymer Chemistry, Vol.47 (No.11). pp. 2882-2891. doi:10.1002/pola.23364

Wang, Jing, Gibson, Matthew I., Barbey, Raphaël, Xiao, Shou-Jun and Klok, Harm-Anton (2009) Nonfouling polypeptide brushes via surface-initiated polymerization of Nε-oligo(ethylene glycol)succinate-L-lysine N-carboxyanhydride. Macromolecular Rapid Communications, Vol.30 (No.9-10). pp. 845-850. doi:10.1002/marc.200800744

Gibson, Matthew I., Barker, Carl A., Spain, Sebastian G., Albertin, Luca and Cameron, Neil R. (2009) Inhibition of ice crystal growth by synthetic glycopolymers : implications for the rational design of antifreeze glycoprotein mimics. Biomacromolecules, Vol.10 (No.2). pp. 328-333. doi:10.1021/bm801069x

2008

Gauthier, Marc A., Gibson, Matthew I. and Klok, Harm-Anton (2008) Synthesis of functional polymers by post-polymerization modification. Angewandte Chemie International Edition, Vol.48 (No.1). pp. 48-58. doi:10.1002/anie.200801951

Gibson, Matthew I. and Cameron, Neil R. (2008) Organogelation of sheet–helix diblock copolypeptides. Angewandte Chemie International Edition, Vol.47 (No.28). pp. 5160-5162. doi:10.1002/anie.200801056

2007

Gibson, Matthew I., Hunt, Gregory J. and Cameron, Neil R. (2007) Improved synthesis of O-linked, and first synthesis of S- linked, carbohydrate functionalised N-carboxyanhydrides (glycoNCAs). Organic & Biomolecular Chemistry, Vol.5 (No.17). pp. 2756-2757. doi:10.1039/b707563d

Spain, Sebastian G., Gibson, Matthew I. and Cameron, Neil R. (2007) Recent advances in the synthesis of well-defined glycopolymers. Journal of Polymer Science Part A: Polymer Chemistry, Vol.45 (No.11). pp. 2059-2072. doi:10.1002/pola.22106