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A tautoleptic approach to chiral hydrogen-bonded supramolecular tubular polymers with large cavity

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Neniškis, Algirdas, Račkauskaitė, Dovilė, Shi, Qixun, Robertson, Aiden, Marsh, Andrew, Ulčinas, Artūras, Valiokas, Ramūnas, Brown, Steven P., Warnmark, Kenneth and Orentas, Edvinas (2018) A tautoleptic approach to chiral hydrogen-bonded supramolecular tubular polymers with large cavity. Chemistry - A European Journal, 24 (53). pp. 14028-14033. doi:10.1002/chem.201803701 ISSN 0947-6539.

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Official URL: http://dx.doi.org/10.1002/chem.201803701

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Abstract

A new strategy towards tubular hydrogen‐bonded polymers based on the self‐assembly of isocytosine tautomers in orthogonal directions is proposed and experimentally verified, including by 1H fast magic‐angle spinning (MAS) solid‐state NMR. The molecular tubes obtained possess large internal diameter and tailor‐made outer functionalities rendering them potential candidates for a number of applications.

Item Type: Journal Article
Divisions: Faculty of Science, Engineering and Medicine > Science > Chemistry
Faculty of Science, Engineering and Medicine > Science > Physics
Journal or Publication Title: Chemistry - A European Journal
Publisher: Wiley
ISSN: 0947-6539
Official Date: September 2018
Dates:
DateEvent
September 2018Published
2 August 2018Available
2 August 2018Accepted
Volume: 24
Number: 53
Page Range: pp. 14028-14033
DOI: 10.1002/chem.201803701
Status: Peer Reviewed
Publication Status: Published
Reuse Statement (publisher, data, author rights): This is the pre-peer reviewed version of the following article: Neniškis, A. , Račkauskaitė, D. , Shi, Q. , Robertson, A. , Marsh, A. , Ulčinas, A. , Valiokas, R. , Brown, S. , Warnmark, K. and Orentas, E. (2018), A Tautoleptic Approach to Chiral Hydrogen‐Bonded Supramolecular Tubular Polymers with Large Cavity. Chem. Eur. J. doi:10.1002/chem.201803701, which has been published in final form at http://dx.doi.org/10.1002/chem.201803701. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Access rights to Published version: Restricted or Subscription Access
Date of first compliant deposit: 31 August 2018
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