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Synthesis of a nanoscale Cu(ii)31-oxo-carboxylate cluster, and effect of Cu–oxo cluster size on visible-light absorption
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Barnes, Thomas J., Payne, Jack and Pike, Sebastian D. (2022) Synthesis of a nanoscale Cu(ii)31-oxo-carboxylate cluster, and effect of Cu–oxo cluster size on visible-light absorption. Chemical Communications . doi:10.1039/D2CC05478G ISSN 1359-7345. (In Press)
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WRAP-Synthesis-of-a-nanoscale-Cu-ii-31-oxo-carboxylate-cluster-and-effect-of-Cu-oxo-cluster-size-on-visible-light-absorption-Pike-2022.pdf - Published Version - Requires a PDF viewer. Available under License Creative Commons Attribution. Download (1085Kb) | Preview |
Official URL: http://dx.doi.org/10.1039/D2CC05478G
Abstract
Cu16–Cu31 Cu(II)-oxo-carboxylate clusters are reported, including those with condensed 1.5 nm Cu–O cores supported exclusively by O-donor ligands. A size–colour correlation is observed due to a red-shift of the charge transfer absorption band on increasing size; hence these clusters sit between small molecules and (black) CuO nanostructures.
| Item Type: | Journal Article | ||||||||||||
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| Subjects: | Q Science > QC Physics Q Science > QD Chemistry T Technology > TK Electrical engineering. Electronics Nuclear engineering |
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| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||||||
| Library of Congress Subject Headings (LCSH): | Metallic oxides -- Synthesis, Photocatalysis, Light absorption , Metal oxide semiconductors | ||||||||||||
| Journal or Publication Title: | Chemical Communications | ||||||||||||
| Publisher: | Royal Society of Chemistry | ||||||||||||
| ISSN: | 1359-7345 | ||||||||||||
| Official Date: | 2022 | ||||||||||||
| Dates: |
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| DOI: | 10.1039/D2CC05478G | ||||||||||||
| Status: | Peer Reviewed | ||||||||||||
| Publication Status: | In Press | ||||||||||||
| Access rights to Published version: | Open Access (Creative Commons) | ||||||||||||
| Date of first compliant deposit: | 5 December 2022 | ||||||||||||
| Date of first compliant Open Access: | 6 December 2022 | ||||||||||||
| RIOXX Funder/Project Grant: |
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