Tait, Steven L., Wang, Yeliang, Costantini, Giovanni, Lin, Nian, Baraldi, Alessandro, Esch, Friedrich, Petaccia, Luca, Lizzit, Silvano and Kern, K. (2008) Metal−organic coordination interactions in Fe−Terephthalic acid networks on Cu(100). Journal of the American Chemical Society, Vol.130 (No.6). pp. 2108-2113. doi:10.1021/ja0778186

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Abstract

Metal−organic coordination interactions are prime candidates for the formation of self-assembled, nanometer-scale periodic networks with room-temperature structural stability. We present X-ray photoelectron spectroscopy measurements of such networks at the Cu(100) surface which provide clear evidence for genuine metal−organic coordination. This is evident as binding energy shifts in the O 1s and Fe 3p photoelectron peaks, corresponding to O and Fe atoms involved in the coordination. Our results provide the first clear evidence for charge-transfer coordination in metal−organic networks at surfaces and demonstrate a well-defined oxidation state for the coordinated Fe ions.

Item Type:	Journal Article
Subjects:	Q Science > QD Chemistry Q Science > QP Physiology
Divisions:	Faculty of Science > Chemistry
Library of Congress Subject Headings (LCSH):	Supramolecular organometallic chemistry, Metal organic chemical vapor deposition, Terephthalic acid, Iron, Copper, Charge transfer in biology
Journal or Publication Title:	Journal of the American Chemical Society
Publisher:	American Chemical Society
ISSN:	0002-7863
Official Date:	2008
Dates:	Date Event 2008 Published
Volume:	Vol.130
Number:	No.6
Page Range:	pp. 2108-2113
DOI:	10.1021/ja0778186
Status:	Peer Reviewed
Publication Status:	Published

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