Metal−organic coordination interactions in Fe−Terephthalic acid networks on Cu(100)
Tait, Steven L., Wang, Yeliang, Costantini, Giovanni, Lin, Nian, Baraldi, Alessandro, Esch, Friedrich, Petaccia, Luca, Lizzit, Silvano and Kern, K.. (2008) Metal−organic coordination interactions in Fe−Terephthalic acid networks on Cu(100). Journal of the American Chemical Society, Vol.130 (No.6). pp. 2108-2113. ISSN 0002-7863Full text not available from this repository.
Official URL: http://dx.doi.org/10.1021/ja0778186
Metal−organic coordination interactions are prime candidates for the formation of self-assembled, nanometer-scale periodic networks with room-temperature structural stability. We present X-ray photoelectron spectroscopy measurements of such networks at the Cu(100) surface which provide clear evidence for genuine metal−organic coordination. This is evident as binding energy shifts in the O 1s and Fe 3p photoelectron peaks, corresponding to O and Fe atoms involved in the coordination. Our results provide the first clear evidence for charge-transfer coordination in metal−organic networks at surfaces and demonstrate a well-defined oxidation state for the coordinated Fe ions.
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry
Q Science > QP Physiology
|Divisions:||Faculty of Science > Chemistry|
|Library of Congress Subject Headings (LCSH):||Supramolecular organometallic chemistry, Metal organic chemical vapor deposition, Terephthalic acid, Iron, Copper, Charge transfer in biology|
|Journal or Publication Title:||Journal of the American Chemical Society|
|Publisher:||American Chemical Society|
|Page Range:||pp. 2108-2113|
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