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Metal−organic coordination interactions in Fe−Terephthalic acid networks on Cu(100)
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Tait, Steven L., Wang, Yeliang, Costantini, Giovanni, Lin, Nian, Baraldi, Alessandro, Esch, Friedrich, Petaccia, Luca, Lizzit, Silvano and Kern, K.. (2008) Metal−organic coordination interactions in Fe−Terephthalic acid networks on Cu(100). Journal of the American Chemical Society, Vol.130 (No.6). pp. 2108-2113. ISSN 0002-7863
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Official URL: http://dx.doi.org/10.1021/ja0778186
Abstract
Metal−organic coordination interactions are prime candidates for the formation of self-assembled, nanometer-scale periodic networks with room-temperature structural stability. We present X-ray photoelectron spectroscopy measurements of such networks at the Cu(100) surface which provide clear evidence for genuine metal−organic coordination. This is evident as binding energy shifts in the O 1s and Fe 3p photoelectron peaks, corresponding to O and Fe atoms involved in the coordination. Our results provide the first clear evidence for charge-transfer coordination in metal−organic networks at surfaces and demonstrate a well-defined oxidation state for the coordinated Fe ions.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QD Chemistry Q Science > QP Physiology |
| Divisions: | Faculty of Science > Chemistry |
| Library of Congress Subject Headings (LCSH): | Supramolecular organometallic chemistry, Metal organic chemical vapor deposition, Terephthalic acid, Iron, Copper, Charge transfer in biology |
| Journal or Publication Title: | Journal of the American Chemical Society |
| Publisher: | American Chemical Society |
| ISSN: | 0002-7863 |
| Date: | 2008 |
| Volume: | Vol.130 |
| Number: | No.6 |
| Page Range: | pp. 2108-2113 |
| Identification Number: | 10.1021/ja0778186 |
| Status: | Peer Reviewed |
| Publication Status: | Published |
| URI: | http://wrap.warwick.ac.uk/id/eprint/40310 |
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