Ma, Xiaoping, Zhang, Lu, Xu, Chengchao, Dong, Qingxin, Walton, Richard I., Li, Zi-An, Shi, Honglong, Chen, Genfu, Hu, Jiangping, Li, Jianqi and Yang, Huaixin (2020) The intercalation of 1,10-phenanthroline into layered NiPS3 via iron dopant seeding. Chemical Communications, 56 (33). pp. 4603-4606. doi:10.1039/D0CC00636J ISSN 1359-7345.
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Abstract
Using 2% percent of iron dopants as reaction active sites yields a series of single crystals of 1,10-phenanthroline intercalated NiPS3, via solution reaction with aniline chloride, not possible by direct reaction. Experimental magnetic susceptibility measurements demonstrate that 1,10-phenanthroline intercalation suppresses the anti-ferromagnetism ordering at around 150 K in Fe0.02Ni0.98PS3, and gives rise to a ferrimagnetic phase transition at the temperature around 75 K. A intercalation mechanism is proposed for the reaction, and this dopant seeding method provides a new approach for intercalation into layered materials.
| Item Type: | Journal Article |
|---|---|
| Subjects: | Q Science > QC Physics Q Science > QD Chemistry |
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry |
| Library of Congress Subject Headings (LCSH): | Antiferromagnetism, Ferrimagnetism, Transition metal compounds |
| Journal or Publication Title: | Chemical Communications |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| Official Date: | 28 April 2020 |
| Dates: | Date Event 28 April 2020 Published 18 March 2020 Available 17 March 2020 Accepted |
| Volume: | 56 |
| Number: | 33 |
| Page Range: | pp. 4603-4606 |
| DOI: | 10.1039/D0CC00636J |
| Status: | Peer Reviewed |
| Publication Status: | Published |
| Access rights to Published version: | Restricted or Subscription Access |
| Date of first compliant deposit: | 19 March 2020 |
| Date of first compliant Open Access: | 18 March 2021 |
| RIOXX Funder/Project Grant: | Project/Grant ID RIOXX Funder Name Funder ID 2016YFA0300303, National Basic Research Program of China (973 Program) 2017YFA0504703 National Basic Research Program of China (973 Program) 2017YFA0302904 National Basic Research Program of China (973 Program) 2017YFA0303000 National Basic Research Program of China (973 Program) 2015CB921304 National Basic Research Program of China (973 Program) |
| URI: | https://wrap.warwick.ac.uk/134603/ |
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